% IMPORTANT: The following is UTF-8 encoded. This means that in the presence
% of non-ASCII characters, it will not work with BibTeX 0.99 or older.
% Instead, you should use an up-to-date BibTeX implementation like “bibtex8” or
% “biber”.
@ARTICLE{Lennartz:19029,
author = {Lennartz, M. C. and Atodiresei, N. and Caciuc, V. and
Karthäuser, S.},
title = {{I}dentifying {M}olecular {O}rbital {E}nergies by
{D}istance-{D}ependent {T}ransition {V}oltage
{S}pectroscopy},
journal = {The journal of physical chemistry / C},
volume = {115},
issn = {1932-7447},
address = {Washington, DC},
publisher = {Soc.},
reportid = {PreJuSER-19029},
pages = {15025 - 15030},
year = {2011},
note = {This work was funded by the DFG (Grant SPP1243). The
computations were performed at JUROPA and JUGENE
supercomputers at the Julich Supercomputer Centre,
Forschungszentrum Julich, Germany.},
abstract = {Besides current-voltage spectroscopy, also transition
voltage spectroscopy (TVS) becomes an interesting tool to
investigate the energetic position of the molecular orbitals
involved in the tunneling process. We used scanning
tunneling spectroscopy to perform both spectroscopy
techniques as a function of the tip-substrate distance.
Employing our model system, benzoic acid on a Cu(110)
surface, we could observe a step in the transition voltage
using distance-dependent TVS. Combining the spectroscopic
results with density functional theory based calculations,
it was possible to identify the molecular orbitals
responsible for charge transport. Moreover, it was found
that different molecular orbitals are responsible for charge
transport if varying STM tip-substrate distances are
examined.},
keywords = {J (WoSType)},
cin = {IAS-1 / JARA-FIT / JARA-SIM / PGI-1 / PGI-7},
ddc = {540},
cid = {I:(DE-Juel1)IAS-1-20090406 / $I:(DE-82)080009_20140620$ /
I:(DE-Juel1)VDB1045 / I:(DE-Juel1)PGI-1-20110106 /
I:(DE-Juel1)PGI-7-20110106},
pnm = {Grundlagen für zukünftige Informationstechnologien},
pid = {G:(DE-Juel1)FUEK412},
shelfmark = {Chemistry, Physical / Nanoscience $\&$ Nanotechnology /
Materials Science, Multidisciplinary},
typ = {PUB:(DE-HGF)16},
UT = {WOS:000293192100073},
doi = {10.1021/jp204240n},
url = {https://juser.fz-juelich.de/record/19029},
}