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024 7 _ |2 DOI
|a 10.1039/c1sm05555k
024 7 _ |2 WOS
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037 _ _ |a PreJuSER-19072
041 _ _ |a eng
082 _ _ |a 530
084 _ _ |2 WoS
|a Chemistry, Physical
084 _ _ |2 WoS
|a Materials Science, Multidisciplinary
084 _ _ |2 WoS
|a Physics, Multidisciplinary
084 _ _ |2 WoS
|a Polymer Science
100 1 _ |0 P:(DE-Juel1)VDB79677
|a Nusser, K.
|b 0
|u FZJ
245 _ _ |a Microscopic Origin of the Terminal Relaxation Time in Polymer Nanocomposites: An Experimental Precedent
260 _ _ |a Cambridge
|b Royal Society of Chemistry (RSC)
|c 2011
300 _ _ |a 79888 - 7991
336 7 _ |a Journal Article
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336 7 _ |a article
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440 _ 0 |0 16881
|a Soft Matter
|v 7
|x 1744-683X
|y 18
500 _ _ |a The authors thank L. Willner for the synthesis of the used polymers. K. Nusser gratefully acknowledges the financial support of the Evonik Foundation.
520 _ _ |a By means of rheology and neutron spin echo spectroscopy, both a macroscopic and a microscopic view on the relaxation dynamics of polymers in the presence of non-attractive nanoparticles could be realized. The results enabled us to show a direct correlation between the microscopically observed confinement length and the macroscopically measured dissipation maximum, which corresponds to the terminal relaxation time. Moreover, the impact of nanoparticle presence on the effectiveness of polymer contour length fluctuations and constraint release is discussed.
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|a Schneider, G.J.
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700 1 _ |0 P:(DE-Juel1)130917
|a Richter, D.
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773 _ _ |0 PERI:(DE-600)2191476-X
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|g Vol. 7, p. 79888 - 7991
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|t Soft matter
|v 7
|x 1744-683X
|y 2011
856 7 _ |u http://dx.doi.org/10.1039/c1sm05555k
856 4 _ |u https://juser.fz-juelich.de/record/19072/files/FZJ-19072.pdf
|y Published under German "Allianz" Licensing conditions on 2011-07-04. Available in OpenAccess from 2012-07-04
|z Published final document.
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