000019536 001__ 19536
000019536 005__ 20230426083031.0
000019536 0247_ $$2DOI$$a10.1103/PhysRevB.84.195440
000019536 0247_ $$2WOS$$aWOS:000296866000012
000019536 0247_ $$2Handle$$a2128/10888
000019536 037__ $$aPreJuSER-19536
000019536 041__ $$aeng
000019536 082__ $$a530
000019536 084__ $$2WoS$$aPhysics, Condensed Matter
000019536 1001_ $$0P:(DE-Juel1)VDB73518$$aSoubatch, S.$$b0$$uFZJ
000019536 245__ $$aStructure and growth of tetracene on Ag(111)
000019536 260__ $$aCollege Park, Md.$$bAPS$$c2011
000019536 300__ $$a195440
000019536 3367_ $$0PUB:(DE-HGF)16$$2PUB:(DE-HGF)$$aJournal Article
000019536 3367_ $$2DataCite$$aOutput Types/Journal article
000019536 3367_ $$00$$2EndNote$$aJournal Article
000019536 3367_ $$2BibTeX$$aARTICLE
000019536 3367_ $$2ORCID$$aJOURNAL_ARTICLE
000019536 3367_ $$2DRIVER$$aarticle
000019536 440_0 $$04919$$aPhysical Review B$$v84$$x1098-0121$$y19
000019536 500__ $$3POF3_Assignment on 2016-02-29
000019536 500__ $$aWe thank M. Sokolowski (University of Bonn), B. Voigtlander (Forschungszentrum Julich), G. Meyer (IBM Research, Zurich), and S. Folsch (Paul-Drude-Institute, Berlin) for helpful discussion. This work was partially supported by the Deutsche Forschungsgemeinschaft (DFG) via priority program 1121 "Organic field effect transistors: structural and dynamic properties" and the project TA244.
000019536 520__ $$aThe structure of the tetracene/Ag(111) interface in the coverage range theta = 0 to 2.4 ML is studied with scanning tunneling microscopy (STM) at 8 K and with low energy electron diffraction (LEED) at T = 300 ... 100 K. For theta less than or similar to 0.01 ML, one-dimensional (1D) diffusion of single molecules along < 01 (1) over bar >-directions is observed even at 8 K. For 0.1 ML < theta < 0.5 ML molecules are homogeneously distributed over the surface forming a disordered phase (static at T = 8 K, dynamic at T = 25 K), indicating a repulsive intermolecular interaction (delta-phase). For theta greater than or similar to 0.5 ML, local ordering in the commensurate gamma-phase is observed. Further increase of the coverage yields a compressed monolayer (ML) phase (theta = 1 ML) with point-on-line registry (alpha-phase). The interaction between molecules has been calculated with the force-field approach to rationalize the molecular packing motifs in the various phases. Under most circumstances molecule-molecule interactions are repulsive, in agreement with experimental findings. A simulation of the adsorption up to theta = 1 ML according to the random sequential adsorption (RSA) algorithm shows that the disorder-to-order transition from the delta- to gamma-phase occurs close to random close packing (RCP), theta = 0.5-0.6 ML. Since tetracene molecules are a two-dimensional (2D) representation of Onsager's hard rod model, this suggests that this phase transition is driven both energetically and entropically. For theta approximate to 2.23 ML a metastable bilayer phase with point-on-line coincidence is observed (beta-phase). The basic structural unit of this phase is a triplet of molecules that are tilted along the long molecular axis against each other; at least one of these molecules is tilted out of the surface plane. Within the beta-phase a superstructure of alternating rotation domains is observed. This superstructure has a period of 7.4 nm. The molecular packing in the beta-phase resembles the packing in the bulk crystal structure of tetracene, its formation can therefore be interpreted as incipient pseudomorphic growth of tetracene on Ag(111). However, pseudomorphic growth cannot be continued beyond the beta-phase.
000019536 536__ $$0G:(DE-Juel1)FUEK412$$2G:(DE-HGF)$$aGrundlagen für zukünftige Informationstechnologien$$cP42$$x0
000019536 542__ $$2Crossref$$i2011-11-09$$uhttp://link.aps.org/licenses/aps-default-license
000019536 588__ $$aDataset connected to Web of Science
000019536 650_7 $$2WoSType$$aJ
000019536 7001_ $$0P:(DE-Juel1)VDB93047$$aKröger, I.$$b1$$uFZJ
000019536 7001_ $$0P:(DE-Juel1)VDB77884$$aKumpf, C.$$b2$$uFZJ
000019536 7001_ $$0P:(DE-Juel1)128791$$aTautz, F.S.$$b3$$uFZJ
000019536 77318 $$2Crossref$$3journal-article$$a10.1103/physrevb.84.195440$$bAmerican Physical Society (APS)$$d2011-11-09$$n19$$p195440$$tPhysical Review B$$v84$$x1098-0121$$y2011
000019536 773__ $$0PERI:(DE-600)2844160-6$$a10.1103/PhysRevB.84.195440$$gVol. 84, p. 195440$$n19$$p195440$$q84<195440$$tPhysical review / B$$v84$$x1098-0121$$y2011
000019536 8567_ $$uhttp://dx.doi.org/10.1103/PhysRevB.84.195440
000019536 8564_ $$uhttps://juser.fz-juelich.de/record/19536/files/PhysRevB.84.195440.pdf$$yOpenAccess
000019536 8564_ $$uhttps://juser.fz-juelich.de/record/19536/files/PhysRevB.84.195440.gif?subformat=icon$$xicon$$yOpenAccess
000019536 8564_ $$uhttps://juser.fz-juelich.de/record/19536/files/PhysRevB.84.195440.jpg?subformat=icon-180$$xicon-180$$yOpenAccess
000019536 8564_ $$uhttps://juser.fz-juelich.de/record/19536/files/PhysRevB.84.195440.jpg?subformat=icon-700$$xicon-700$$yOpenAccess
000019536 8564_ $$uhttps://juser.fz-juelich.de/record/19536/files/PhysRevB.84.195440.pdf?subformat=pdfa$$xpdfa$$yOpenAccess
000019536 909CO $$ooai:juser.fz-juelich.de:19536$$pdnbdelivery$$pVDB$$pdriver$$popen_access$$popenaire
000019536 915__ $$0LIC:(DE-HGF)APS-112012$$2HGFVOC$$aAmerican Physical Society Transfer of Copyright Agreement
000019536 915__ $$0StatID:(DE-HGF)0510$$2StatID$$aOpenAccess
000019536 915__ $$0StatID:(DE-HGF)0010$$aJCR/ISI refereed
000019536 9141_ $$y2011
000019536 9101_ $$0I:(DE-588b)5008462-8$$6P:(DE-Juel1)128791$$aForschungszentrum Jülich$$b3$$kFZJ
000019536 9131_ $$0G:(DE-Juel1)FUEK412$$aDE-HGF$$bSchlüsseltechnologien$$kP42$$lGrundlagen für zukünftige Informationstechnologien (FIT)$$vGrundlagen für zukünftige Informationstechnologien$$x0
000019536 9132_ $$0G:(DE-HGF)POF3-529H$$1G:(DE-HGF)POF3-520$$2G:(DE-HGF)POF3-500$$aDE-HGF$$bKey Technologies$$lFuture Information Technology - Fundamentals, Novel Concepts and Energy Efficiency (FIT)$$vAddenda$$x0
000019536 9201_ $$0I:(DE-Juel1)PGI-3-20110106$$gPGI$$kPGI-3$$lFunktionale Nanostrukturen an Oberflächen$$x0
000019536 9201_ $$0I:(DE-82)080009_20140620$$gJARA$$kJARA-FIT$$lJülich-Aachen Research Alliance - Fundamentals of Future Information Technology$$x1
000019536 970__ $$aVDB:(DE-Juel1)134392
000019536 9801_ $$aFullTexts
000019536 980__ $$aVDB
000019536 980__ $$aConvertedRecord
000019536 980__ $$ajournal
000019536 980__ $$aI:(DE-Juel1)PGI-3-20110106
000019536 980__ $$aI:(DE-82)080009_20140620
000019536 980__ $$aUNRESTRICTED
000019536 981__ $$aI:(DE-Juel1)VDB881
000019536 999C5 $$2Crossref$$9-- missing cx lookup --$$a10.1016/j.susc.2004.10.031
000019536 999C5 $$2Crossref$$9-- missing cx lookup --$$a10.1038/nphys1176
000019536 999C5 $$2Crossref$$9-- missing cx lookup --$$a10.1016/j.chemphys.2006.01.006
000019536 999C5 $$2Crossref$$9-- missing cx lookup --$$a10.1126/science.1159455
000019536 999C5 $$2Crossref$$9-- missing cx lookup --$$a10.1103/PhysRevLett.90.016104
000019536 999C5 $$2Crossref$$9-- missing cx lookup --$$a10.1038/35087532
000019536 999C5 $$2Crossref$$9-- missing cx lookup --$$a10.1103/PhysRevLett.94.056104
000019536 999C5 $$2Crossref$$9-- missing cx lookup --$$a10.1126/science.1163338
000019536 999C5 $$2Crossref$$9-- missing cx lookup --$$a10.1103/PhysRevB.81.035423
000019536 999C5 $$2Crossref$$9-- missing cx lookup --$$a10.1021/jp709826q
000019536 999C5 $$2Crossref$$9-- missing cx lookup --$$a10.1103/PhysRevLett.104.036102
000019536 999C5 $$2Crossref$$9-- missing cx lookup --$$a10.1002/pssa.200723447
000019536 999C5 $$2Crossref$$9-- missing cx lookup --$$a10.1088/1367-2630/12/8/083038
000019536 999C5 $$2Crossref$$9-- missing cx lookup --$$a10.1103/PhysRevB.83.085416
000019536 999C5 $$2Crossref$$9-- missing cx lookup --$$a10.1103/PhysRevB.69.075416
000019536 999C5 $$2Crossref$$9-- missing cx lookup --$$a10.1103/PhysRevB.71.235405
000019536 999C5 $$2Crossref$$9-- missing cx lookup --$$a10.1002/1521-4095(200102)13:4<227::AID-ADMA227>3.0.CO;2-P
000019536 999C5 $$2Crossref$$9-- missing cx lookup --$$a10.1142/S0217984906011189
000019536 999C5 $$2Crossref$$9-- missing cx lookup --$$a10.1021/la901760j
000019536 999C5 $$2Crossref$$9-- missing cx lookup --$$a10.1111/j.1749-6632.1949.tb27296.x
000019536 999C5 $$2Crossref$$9-- missing cx lookup --$$a10.1016/0039-6028(89)90464-0
000019536 999C5 $$2Crossref$$9-- missing cx lookup --$$a10.1016/S0039-6028(03)00592-2
000019536 999C5 $$2Crossref$$9-- missing cx lookup --$$a10.1063/1.1826229
000019536 999C5 $$2Crossref$$9-- missing cx lookup --$$a10.1088/1367-2630/11/12/125010
000019536 999C5 $$2Crossref$$9-- missing cx lookup --$$a10.1021/cg101230j
000019536 999C5 $$2Crossref$$9-- missing cx lookup --$$a10.1021/ja0730516
000019536 999C5 $$2Crossref$$9-- missing cx lookup --$$a10.1107/S0365110X62000699
000019536 999C5 $$2Crossref$$9-- missing cx lookup --$$a10.1002/adma.200602072
000019536 999C5 $$2Crossref$$9-- missing cx lookup --$$a10.1021/cr941014o
000019536 999C5 $$2Crossref$$9-- missing cx lookup --$$a10.1103/PhysRevB.76.121302
000019536 999C5 $$2Crossref$$9-- missing cx lookup --$$a10.1103/PhysRevB.77.113404
000019536 999C5 $$2Crossref$$9-- missing cx lookup --$$a10.1103/PhysRevLett.103.136101
000019536 999C5 $$2Crossref$$9-- missing cx lookup --$$a10.1016/S0039-6028(87)80476-4
000019536 999C5 $$2Crossref$$9-- missing cx lookup --$$a10.1063/1.455720
000019536 999C5 $$2Crossref$$9-- missing cx lookup --$$a10.1103/PhysRevLett.102.177405
000019536 999C5 $$2Crossref$$9-- missing cx lookup --$$a10.1002/sia.1775
000019536 999C5 $$2Crossref$$9-- missing cx lookup --$$a10.1103/PhysRevB.70.245415
000019536 999C5 $$2Crossref$$9-- missing cx lookup --$$a10.1016/S0009-2614(99)01457-8
000019536 999C5 $$1H. Ishii$$2Crossref$$oH. Ishii Conjugated Polymer and Molecular Interfaces 2002$$tConjugated Polymer and Molecular Interfaces$$y2002
000019536 999C5 $$2Crossref$$9-- missing cx lookup --$$a10.1103/PhysRevB.76.165436
000019536 999C5 $$2Crossref$$9-- missing cx lookup --$$a10.1103/PhysRevLett.88.028301
000019536 999C5 $$2Crossref$$9-- missing cx lookup --$$a10.1103/PhysRevLett.85.2981
000019536 999C5 $$2Crossref$$9-- missing cx lookup --$$a10.1088/0953-8984/12/1/103
000019536 999C5 $$2Crossref$$9-- missing cx lookup --$$a10.1016/S0039-6028(96)00994-6
000019536 999C5 $$2Crossref$$9-- missing cx lookup --$$a10.1103/PhysRevLett.68.3801
000019536 999C5 $$2Crossref$$9-- missing cx lookup --$$a10.1038/365035a0
000019536 999C5 $$2Crossref$$9-- missing cx lookup --$$a10.1103/PhysRevE.64.051403
000019536 999C5 $$2Crossref$$9-- missing cx lookup --$$a10.1088/0953-8984/6/23A/008
000019536 999C5 $$2Crossref$$9-- missing cx lookup --$$a10.1063/1.1305887
000019536 999C5 $$2Crossref$$9-- missing cx lookup --$$a10.1088/0953-8984/6/23A/008
000019536 999C5 $$2Crossref$$9-- missing cx lookup --$$a10.1103/PhysRevA.27.1053
000019536 999C5 $$2Crossref$$9-- missing cx lookup --$$a10.1088/0022-3727/2/6/311
000019536 999C5 $$2Crossref$$9-- missing cx lookup --$$a10.1038/nature06981
000019536 999C5 $$1P. Schaaf$$2Crossref$$oP. Schaaf Lecture Notes in Physics: 25 Years of Non-Equilibrium Statistical Mechanics 1995$$tLecture Notes in Physics: 25 Years of Non-Equilibrium Statistical Mechanics$$y1995
000019536 999C5 $$2Crossref$$9-- missing cx lookup --$$a10.1103/PhysRevLett.94.026803
000019536 999C5 $$2Crossref$$9-- missing cx lookup --$$a10.1103/PhysRevB.74.041402
000019536 999C5 $$2Crossref$$9-- missing cx lookup --$$a10.1103/PhysRevLett.81.4464
000019536 999C5 $$2Crossref$$9-- missing cx lookup --$$a10.1016/0039-6028(95)00509-9
000019536 999C5 $$2Crossref$$9-- missing cx lookup --$$a10.1103/PhysRevB.56.7656
000019536 999C5 $$2Crossref$$9-- missing cx lookup --$$a10.1063/1.1696269
000019536 999C5 $$2Crossref$$9-- missing cx lookup --$$a10.1103/PhysRev.37.682
000019536 999C5 $$2Crossref$$9-- missing cx lookup --$$a10.1103/PhysRevB.49.11297
000019536 999C5 $$2Crossref$$9-- missing cx lookup --$$a10.1021/j100785a001
000019536 999C5 $$2Crossref$$9-- missing cx lookup --$$a10.1107/S0365110X61002151
000019536 999C5 $$2Crossref$$9-- missing cx lookup --$$a10.1063/1.2432410