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@PHDTHESIS{Blsner:19746,
author = {Bläsner, Martin},
title = {{E}ntwicklung eines bipolaren flugzeuggetragenen
{A}erosolmassenspektrometers},
volume = {3984},
issn = {0944-2952},
type = {Dr. (Univ.)},
address = {Jülich},
publisher = {Forschungszentrum Jülich GmbH Zentralbibliothek, Verlag},
reportid = {PreJuSER-19746, Juel-3984},
series = {Berichte des Forschungszentrums Jülich},
pages = {VII, 99 p.},
year = {2002},
note = {Record converted from VDB: 12.11.2012; Bonn, Univ. Diss.
2002},
comment = {.},
booktitle = {.},
abstract = {The aim of this thesis is the development of an aerosol
mass spectrometer designed to determine aerosols in upper
troposphere and the lowermost stratosphere. The instrument
named SPLAT (Single Particle Laser Ablation Time of flight
mass spectrometer) was developed for the integration in a
research aircraft for a flight altitude of about 10 km. The
SPLAT system should be able to provide information about the
size and the chemical composition of an individual aerosol
particle from ambient air. The knowledge of this parameter
is of relevance, because of its important role for
heterogeneous chemical reactions, for ozone depletion and
for cloud formation. Direct effects of aerosol particles,
like e.g. scattering and absorption of sunlight, may cause a
negative or positive forcing of climate in dependence of
size and composition. A differentially pumped inlet system
separates the particles from the gas phase within the SPLAT
system. At high vacuum conditions the sizing takes place
through a laser ray configuration. Two laser rays measure
the velocity of every individual particle. The velocity
depends an the aerodynamic diameter of the particle.
Further, the laser configuration triggers an excimer laser.
A pulse of the excimer laser vaporizes and ionizes the
particle when it reaches the middle of the mass
spectrometer. To determine the mass of the ions formed, they
are detected in a time-of-flight mass spectrometer. Both the
negative and positive ions of a particle can be detected,
because of the bipolar construction of the mass
spectrometer. Thereby for the first time extensive studies
of the size and the chemical composition of individual
aerosol particles are possible for in-flight conditions. The
efficiency of the instrument was verified in numerous
laboratory measurements with particles of known diameter and
known chemical composition. These measurements are further
used to calibrate the Instrument. The participation in the
MINOS field campaign an the island of Crete yielded the
first measurements in ambient aerosol particles.},
cin = {ICG-I},
cid = {I:(DE-Juel1)VDB47},
pnm = {Chemie und Dynamik der Geo-Biosphäre},
pid = {G:(DE-Juel1)FUEK257},
typ = {PUB:(DE-HGF)11 / PUB:(DE-HGF)3},
url = {https://juser.fz-juelich.de/record/19746},
}