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@ARTICLE{Nygard:19750,
author = {Nygard, K. and Kjellander, R. and Sarman, S. and Chodankar,
S. and Perret, E. and Buitenhuis, J. and van der Veen, J.F.},
title = {{A}nisotropic {P}air {C}orrelations and {S}tructure
{F}actors of {C}onfined {H}ard-{S}phere {F}luids: {A}n
{E}xperimental and {T}heoretical {S}tudy},
journal = {Physical review letters},
volume = {108},
issn = {0031-9007},
address = {College Park, Md.},
publisher = {APS},
reportid = {PreJuSER-19750},
pages = {037802},
year = {2012},
note = {The experiment was carried out at the cSAXS beam line of
the Swiss Light Source, Paul Scherrer Institut, Villigen,
Switzerland. We thank the beam line staff for assistance.
One of us (R. K.) gratefully acknowledges support from the
Swedish Research council. The calculations in this work were
supported by the Swedish National Infrastructure for
Computing (SNIC 001-09-152) via PDC.},
abstract = {We address the fundamental question: how are pair
correlations and structure factors of hard-sphere fluids
affected by confinement between hard planar walls at close
distance? For this purpose, we combine x-ray scattering from
colloid-filled nanofluidic channel arrays and
first-principles inhomogeneous liquid-state theory within
the anisotropic Percus-Yevick approximation. The
experimental and theoretical data are in remarkable
agreement at the pair-correlation level, providing the first
quantitative experimental verification of the theoretically
predicted confinement-induced anisotropy of the
pair-correlation functions for the fluid. The description of
confined fluids at this level provides, in the general case,
important insights into the mechanisms of particle-particle
interactions in dense fluids under confinement.},
keywords = {J (WoSType)},
cin = {ICS-3},
ddc = {550},
cid = {I:(DE-Juel1)ICS-3-20110106},
pnm = {BioSoft: Makromolekulare Systeme und biologische
Informationsverarbeitung},
pid = {G:(DE-Juel1)FUEK505},
shelfmark = {Physics, Multidisciplinary},
typ = {PUB:(DE-HGF)16},
UT = {WOS:000299328500025},
doi = {10.1103/PhysRevLett.108.037802},
url = {https://juser.fz-juelich.de/record/19750},
}