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001     19834
005     20240708132749.0
024 7 _ |2 pmid
|a pmid:15017085
024 7 _ |2 DOI
|a 10.1179/1743284710Y.0000000002
024 7 _ |2 WOS
|a WOS:000291551000001
037 _ _ |a PreJuSER-19834
041 _ _ |a eng
082 _ _ |a 600
084 _ _ |2 WoS
|a Materials Science, Multidisciplinary
084 _ _ |2 WoS
|a Metallurgy & Metallurgical Engineering
100 1 _ |0 P:(DE-Juel1)VDB92979
|a Röttger, A.
|b 0
|u FZJ
245 _ _ |a Mechanical properties of thermally sprayed Fe based coatings
260 _ _ |a London [u.a.]
|b Maney Publishing
|c 2011
300 _ _ |a 973 - 982
336 7 _ |a Journal Article
|0 PUB:(DE-HGF)16
|2 PUB:(DE-HGF)
336 7 _ |a Output Types/Journal article
|2 DataCite
336 7 _ |a Journal Article
|0 0
|2 EndNote
336 7 _ |a ARTICLE
|2 BibTeX
336 7 _ |a JOURNAL_ARTICLE
|2 ORCID
336 7 _ |a article
|2 DRIVER
440 _ 0 |0 4205
|a Materials Science and Technology
|v 27
|x 0267-0836
|y 6
500 _ _ |a The authors gratefully acknowledge financial support by the Deutsche Forschungsgemeinschaft within the project 'Thermisches Spritzen von Fe-Basis MMC' (DFG project no. TH531/6-1; VA163/4-1).
520 _ _ |a The synthetic vanadinites (Pb(x)Ca(10-x))(VO4)6F2delta, 1 < x < 9, adopt a P6(3)/m apatite structure with 9.7590 (1) < or = a < or = 10.1179 (1) A and 7.0434 (3) < or = c < or = 7.4021 (1) A. The partitioning of calcium and lead over the AI(4f) and AII(6h) positions is nonstoichiometric with lead preferentially entering the larger AII site. High-resolution electron microscopy showed that samples annealed for 10 h at 1073 K are in disequilibrium with calcium- and lead-rich microdomains co-existing at unit-cell scales. For (Pb5Ca5)(VO4)6F2delta, sintering in excess of 2 weeks is required for the metals to order macroscopically. As annealing progresses, c/a, the partitioning coefficient kPb(AI/AII) and the AIO6 metaprism twist angle (phi) adjust cooperatively to enlarge the apatite channel, and thereby accommodate higher lead content. These results demonstrate that phi is a sensitive measure of disequilibrium and a useful device for monitoring changes in apatite topology as a function of composition.
536 _ _ |0 G:(DE-Juel1)FUEK402
|2 G:(DE-HGF)
|a Rationelle Energieumwandlung
|c P12
|x 0
588 _ _ |a Dataset connected to Web of Science, Pubmed
650 _ 7 |2 WoSType
|a J
653 2 0 |2 Author
|a HVOF
653 2 0 |2 Author
|a Tool steel
653 2 0 |2 Author
|a Wear resistance
653 2 0 |2 Author
|a Mechanical properties
653 2 0 |2 Author
|a Thermal spraying
653 2 0 |2 Author
|a Review
700 1 _ |0 P:(DE-Juel1)VDB1997
|a Weber, S.
|b 1
|u FZJ
700 1 _ |0 P:(DE-Juel1)VDB90949
|a Theisen, W.
|b 2
|u FZJ
700 1 _ |0 P:(DE-Juel1)VDB104516
|a Rajasekeran, B.
|b 3
|u FZJ
700 1 _ |0 P:(DE-Juel1)129670
|a Vassen, R.
|b 4
|u FZJ
773 _ _ |0 PERI:(DE-600)2037367-3
|a 10.1179/1743284710Y.0000000002
|g Vol. 27, p. 973 - 982
|p 973 - 982
|q 27<973 - 982
|t Materials science and technology
|v 27
|x 0267-0836
|y 2011
856 7 _ |u http://dx.doi.org/10.1179/1743284710Y.0000000002
909 C O |o oai:juser.fz-juelich.de:19834
|p VDB
913 1 _ |0 G:(DE-Juel1)FUEK402
|a DE-HGF
|b Energie
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|l Rationelle Energieumwandlung
|v Rationelle Energieumwandlung
|x 0
913 2 _ |0 G:(DE-HGF)POF3-113
|1 G:(DE-HGF)POF3-110
|2 G:(DE-HGF)POF3-100
|a DE-HGF
|b Forschungsbereich Energie
|l Energieeffizienz, Materialien und Ressourcen
|v Methods and Concepts for Material Development
|x 0
914 1 _ |y 2011
915 _ _ |0 StatID:(DE-HGF)0010
|a JCR/ISI refereed
920 1 _ |0 I:(DE-Juel1)IEK-1-20101013
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980 _ _ |a UNRESTRICTED
981 _ _ |a I:(DE-Juel1)IMD-2-20101013

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