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000019963 0247_ $$2DOI$$a10.1002/zaac.201100021
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000019963 084__ $$2WoS$$aChemistry, Inorganic & Nuclear
000019963 1001_ $$0P:(DE-HGF)0$$aBaca, S.G.$$b0
000019963 245__ $$aA Heptanuclear Iron(III) Oxo-Carboxylate Cluster
000019963 260__ $$aWeinheim$$bWiley-VCH$$c2011
000019963 3367_ $$0PUB:(DE-HGF)16$$2PUB:(DE-HGF)$$aJournal Article
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000019963 500__ $$3POF3_Assignment on 2016-02-29
000019963 500__ $$aFinancial support was provided by the German Federal Ministry of Education and Research (Grant MDA 08/022) and the Academy of Sciences of Moldova (Grant No. 09.820.05.10GF). We thank the European Commission for an IIF Marie Curie Fellowship to S. G. B. (POLY-MAG, contract no. 252984).
000019963 520__ $$aA new heptanuclear iron(III) oxide pivalate cluster [Fe7O4(OH)(2)(O2CCMe3)(11)(bpm)(2)(H2O)] (1) (bpm = 2,2'-bipyrimidine) has been prepared and characterized. 1 features an asymmetric {Fe7O6} framework based on two corner-sharing {Fe-4(mu(3)-O)(2)} groups, themselves comprising {Fe-3(mu(3)-O)} motifs that are formally retained from the {Fe6O4} precursor used in thesynthesis of 1. Compared to existing Fe-III oxide carboxylate clusters, the {Fe7O6} fragment in 1 exhibits an unusually high Fe:O ratio, with all seven oxygen sites efficiently mediating magnetic exchange. Correspondingly, 1 shows strong intramolecular antiferromagnetic coupling.
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000019963 65320 $$2Author$$aIron
000019963 65320 $$2Author$$aCluster compounds
000019963 65320 $$2Author$$aCarboxylate ligands
000019963 65320 $$2Author$$aN ligands
000019963 65320 $$2Author$$aMagnetic properties
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000019963 7001_ $$0P:(DE-HGF)0$$aBotezat, O.$$b1
000019963 7001_ $$0P:(DE-HGF)0$$aFilippova, I.$$b2
000019963 7001_ $$0P:(DE-HGF)0$$aSpeldrich, M.$$b3
000019963 7001_ $$0P:(DE-HGF)0$$aJeanneau, E.$$b4
000019963 7001_ $$0P:(DE-Juel1)VDB12080$$aKögerler, P.$$b5$$uFZJ
000019963 773__ $$0PERI:(DE-600)1481139-x$$a10.1002/zaac.201100021$$gVol. 637$$q637$$tZeitschrift für anorganische und allgemeine Chemie$$v637$$x0044-2313$$y2011
000019963 8567_ $$uhttp://dx.doi.org/10.1002/zaac.201100021
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