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@ARTICLE{Baca:19963,
      author       = {Baca, S.G. and Botezat, O. and Filippova, I. and Speldrich,
                      M. and Jeanneau, E. and Kögerler, P.},
      title        = {{A} {H}eptanuclear {I}ron({III}) {O}xo-{C}arboxylate
                      {C}luster},
      journal      = {Zeitschrift für anorganische und allgemeine Chemie},
      volume       = {637},
      issn         = {0044-2313},
      address      = {Weinheim},
      publisher    = {Wiley-VCH},
      reportid     = {PreJuSER-19963},
      year         = {2011},
      note         = {Financial support was provided by the German Federal
                      Ministry of Education and Research (Grant MDA 08/022) and
                      the Academy of Sciences of Moldova (Grant No.
                      09.820.05.10GF). We thank the European Commission for an IIF
                      Marie Curie Fellowship to S. G. B. (POLY-MAG, contract no.
                      252984).},
      abstract     = {A new heptanuclear iron(III) oxide pivalate cluster
                      [Fe7O4(OH)(2)(O2CCMe3)(11)(bpm)(2)(H2O)] (1) (bpm =
                      2,2'-bipyrimidine) has been prepared and characterized. 1
                      features an asymmetric {Fe7O6} framework based on two
                      corner-sharing {Fe-4(mu(3)-O)(2)} groups, themselves
                      comprising {Fe-3(mu(3)-O)} motifs that are formally retained
                      from the {Fe6O4} precursor used in thesynthesis of 1.
                      Compared to existing Fe-III oxide carboxylate clusters, the
                      {Fe7O6} fragment in 1 exhibits an unusually high Fe:O ratio,
                      with all seven oxygen sites efficiently mediating magnetic
                      exchange. Correspondingly, 1 shows strong intramolecular
                      antiferromagnetic coupling.},
      keywords     = {J (WoSType)},
      cin          = {PGI-6},
      ddc          = {540},
      cid          = {I:(DE-Juel1)PGI-6-20110106},
      pnm          = {Grundlagen für zukünftige Informationstechnologien /
                      POLYMAG - Magnetic Coordination Cluster Polymers (252984)},
      pid          = {G:(DE-Juel1)FUEK412 / G:(EU-Grant)252984},
      shelfmark    = {Chemistry, Inorganic $\&$ Nuclear},
      typ          = {PUB:(DE-HGF)16},
      UT           = {WOS:000292334400003},
      doi          = {10.1002/zaac.201100021},
      url          = {https://juser.fz-juelich.de/record/19963},
}