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001     19963
005     20180208222716.0
024 7 _ |2 DOI
|a 10.1002/zaac.201100021
024 7 _ |2 WOS
|a WOS:000292334400003
037 _ _ |a PreJuSER-19963
041 _ _ |a eng
082 _ _ |a 540
084 _ _ |2 WoS
|a Chemistry, Inorganic & Nuclear
100 1 _ |0 P:(DE-HGF)0
|a Baca, S.G.
|b 0
245 _ _ |a A Heptanuclear Iron(III) Oxo-Carboxylate Cluster
260 _ _ |a Weinheim
|b Wiley-VCH
|c 2011
336 7 _ |a Journal Article
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336 7 _ |a Journal Article
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336 7 _ |a ARTICLE
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336 7 _ |a JOURNAL_ARTICLE
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336 7 _ |a article
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440 _ 0 |0 12141
|a Zeitschrift für Anorganische und Allgemeine Chemie
|v 637
|x 0044-2313
|y 7
500 _ _ |3 POF3_Assignment on 2016-02-29
500 _ _ |a Financial support was provided by the German Federal Ministry of Education and Research (Grant MDA 08/022) and the Academy of Sciences of Moldova (Grant No. 09.820.05.10GF). We thank the European Commission for an IIF Marie Curie Fellowship to S. G. B. (POLY-MAG, contract no. 252984).
520 _ _ |a A new heptanuclear iron(III) oxide pivalate cluster [Fe7O4(OH)(2)(O2CCMe3)(11)(bpm)(2)(H2O)] (1) (bpm = 2,2'-bipyrimidine) has been prepared and characterized. 1 features an asymmetric {Fe7O6} framework based on two corner-sharing {Fe-4(mu(3)-O)(2)} groups, themselves comprising {Fe-3(mu(3)-O)} motifs that are formally retained from the {Fe6O4} precursor used in thesynthesis of 1. Compared to existing Fe-III oxide carboxylate clusters, the {Fe7O6} fragment in 1 exhibits an unusually high Fe:O ratio, with all seven oxygen sites efficiently mediating magnetic exchange. Correspondingly, 1 shows strong intramolecular antiferromagnetic coupling.
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536 _ _ |a POLYMAG - Magnetic Coordination Cluster Polymers (252984)
|0 G:(EU-Grant)252984
|c 252984
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|f FP7-PEOPLE-2009-IIF
588 _ _ |a Dataset connected to Web of Science
650 _ 7 |2 WoSType
|a J
653 2 0 |2 Author
|a Iron
653 2 0 |2 Author
|a Cluster compounds
653 2 0 |2 Author
|a Carboxylate ligands
653 2 0 |2 Author
|a N ligands
653 2 0 |2 Author
|a Magnetic properties
700 1 _ |0 P:(DE-HGF)0
|a Botezat, O.
|b 1
700 1 _ |0 P:(DE-HGF)0
|a Filippova, I.
|b 2
700 1 _ |0 P:(DE-HGF)0
|a Speldrich, M.
|b 3
700 1 _ |0 P:(DE-HGF)0
|a Jeanneau, E.
|b 4
700 1 _ |0 P:(DE-Juel1)VDB12080
|a Kögerler, P.
|b 5
|u FZJ
773 _ _ |0 PERI:(DE-600)1481139-x
|a 10.1002/zaac.201100021
|g Vol. 637
|q 637
|t Zeitschrift für anorganische und allgemeine Chemie
|v 637
|x 0044-2313
|y 2011
856 7 _ |u http://dx.doi.org/10.1002/zaac.201100021
909 C O |o oai:juser.fz-juelich.de:19963
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914 1 _ |y 2011
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