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000019997 084__ $$2WoS$$aChemistry, Multidisciplinary
000019997 1001_ $$0P:(DE-Juel1)VDB70617$$aKowalzik, P.$$b0$$uFZJ
000019997 245__ $$aColumnar self-assembly of a 3D-persulfurated coronene asterisk. The dominant role of Aryl-Sulfur bonds
000019997 260__ $$aLondon$$bRSC$$c2012
000019997 300__ $$a477 - 483
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000019997 440_0 $$04599$$aNew Journal of Chemistry$$v36$$x1144-0546$$y2
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000019997 520__ $$aThe synthesis, adsorption behavior, surface structure, and the charge transport properties of a persulfurated coronene asterisk with a 3D-polyaromatic system, namely dodecakis(phenylthio) coronene (DPTC), deposited on HOPG(0001) and Au(111) surfaces, are investigated by means of scanning tunneling microscopy (STM) and spectroscopy (STS). DPTC molecules adsorbed on HOPG(0001) show an orbital mediated tunneling through mainly undisturbed frontier molecular states. DPTC molecules self-assemble on Au(111) into a highly ordered p-stacked columnar "edge-on pattern. The columnar stacking is a gold surface mediated process, as ascertained by fluorescence correlation spectroscopy (FCS). DPTC was monomeric in the precursor solution before assembly. The tunneling spectra of ordered DPTC stacks on Au(111) show an energetic splitting of the frontier molecular states, indicating orbital overlap and supramolecular pi pi interactions of adjacent molecules. DPTCs are sufficiently flexible to facilitate dense 1D stacks. The multiple aryl-sulfur bonds play a dominant role in the modulation of the self-assembly properties of the coronenes which in turn affect their electronic properties. Our results encourage further applications in dendrimer chemistry toward molecular electronics, by using the functionalized coronene core and its multidirectional 3D properties.
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000019997 7001_ $$0P:(DE-HGF)0$$aRathgeber, S.$$b1
000019997 7001_ $$0P:(DE-Juel1)130751$$aKarthäuser, S.$$b2$$uFZJ
000019997 7001_ $$0P:(DE-Juel1)131022$$aWaser, R.$$b3$$uFZJ
000019997 7001_ $$0P:(DE-HGF)0$$aSchnaebele, N.$$b4
000019997 7001_ $$0P:(DE-HGF)0$$aGingras, M.$$b5
000019997 773__ $$0PERI:(DE-600)1472933-7$$a10.1039/c1nj20472f$$gVol. 36, p. 477 - 483$$p477 - 483$$q36<477 - 483$$tNew journal of chemistry$$v36$$x1144-0546$$y2012
000019997 8567_ $$uhttp://dx.doi.org/10.1039/C1NJ20472F
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