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@ARTICLE{Liao:20035,
author = {Liao, L. and dal Maso, M. and Taipale, R. and Rinne, J. and
Ehn, M. and Junninen, H. and Äijälä, M. and Nieminen, T.
and Alekseychik, P. and Hulkkonen, M. and Worsnop, D.R. and
Kerminen, V.-M. and Kulmala, M.},
title = {{M}onoterpene pollution episodes in a forest environment:
indication of anthropogenic origin and association with
aerosol particles},
journal = {Boreal environment research},
volume = {16},
issn = {1239-6095},
address = {Helsinki},
publisher = {Finnish Zoological and Botanical Publishing Board},
reportid = {PreJuSER-20035},
pages = {288 - 303},
year = {2011},
note = {The Authors wish to thank the Maj and Tor Nessling
foundation for financial support (grant no. 2009362), as
well as the Academy of Finland (project no. 123731). This
work has been partly funded by European Commission 6th
Framework programme project EUCAARI (contract no. 0368332).
The financial support by the Academy of Finland Centre of
Excellence program (project no. 1118615) and the Kone
Foundation is gratefully acknowledged.},
abstract = {We used a monoterpene volume mixing ratio dataset measured
from 12 June 2006 to 24 September 2007 and from 1 June 2008
to 3 March 2009 at the SMEAR II station to quantify the
magnitude of anthropogenic monoterpene emissions aside from
biogenic origins, to examine the anthropogenic sources, and
to look at other associated pollutants. We discuss the
relations between increased monoterpene mixing ratios and
particle concentrations. We also characterize chemical
properties of aerosol particles during two monoterpene
pollution episodes in case studies. Out of 580 days
analyzed, anthropogenic monoterpene pollution episodes were
found on 341 $(58.8\%)$ days. The average monoterpene mixing
ratio increased from 0.19 to 0.26 ppbv due to the presence
of anthropogenic monoterpenes, which is equal to an increase
of $36.8\%.$ The observed anthropogenic monoterpenes were
mostly from the Korkeakoski sawmill. Other gas pollutants
might occasionally be emitted during the episodes, but did
not show clear association with anthropogenic monoterpenes.
Aerosol particle concentrations substantially increased
during episodes, and monoterpene mixing ratios showed strong
connections with Aitken mode particles both in number and
volume concentrations. Particles associated with monoterpene
episodes reached a CCN (cloud concentration nucleus) size.
The chemical characterizations of aerosol particles in case
studies show that the increase in aerosol particle mass was
mainly from secondary organic aerosol.},
keywords = {J (WoSType)},
cin = {IEK-8},
ddc = {333.7},
cid = {I:(DE-Juel1)IEK-8-20101013},
pnm = {Atmosphäre und Klima},
pid = {G:(DE-Juel1)FUEK491},
shelfmark = {Environmental Sciences},
typ = {PUB:(DE-HGF)16},
UT = {WOS:000294698900004},
url = {https://juser.fz-juelich.de/record/20035},
}