001     200801
005     20240708133711.0
037 _ _ |a FZJ-2015-03194
100 1 _ |a Urbain, Felix
|0 P:(DE-Juel1)156469
|b 0
|e Corresponding Author
111 2 _ |a EMRS Spring Conference
|c Lille
|d 2015-05-11 - 2015-05-15
|w France
245 _ _ |a Efficient multijunction thin film silicon solar cells with open-circuit voltages up to 2.8 V for the application in photoelectrochemical energy storage devices
260 _ _ |c 2015
336 7 _ |a Conference Presentation
|b conf
|m conf
|0 PUB:(DE-HGF)6
|s 1432017252_25880
|2 PUB:(DE-HGF)
|x Other
336 7 _ |a Conference Paper
|0 33
|2 EndNote
336 7 _ |a Other
|2 DataCite
336 7 _ |a LECTURE_SPEECH
|2 ORCID
336 7 _ |a conferenceObject
|2 DRIVER
336 7 _ |a INPROCEEDINGS
|2 BibTeX
520 _ _ |a We report on the development of multijunction solar cells for the integration in photoelectrochemical devices for hydrogen production. Hydrogen, as a storable chemical fuel, can be generated through photoelectrolysis of water, a chemical reaction which requires potentials, i.e. photovoltages over 1.8V to run autonomously. The exact voltage needed varies with the used catalysts. The photocurrent at the respective required voltage determines the solar-to-hydrogen device efficiency. It is therefore important to develop solar cells which can cover up a wide voltage (VOC and VMPP) range in combination with high photocurrents. This high photovoltage/high photocurrent tradeoff can be solved by multijunction solar cells made of amorphous (a-Si:H) and microcrystalline (μc-Si:H) silicon.We developed a-Si:H/a Si:H tandem, a Si:H/µc Si:H/µc Si:H and a Si:H/a Si:H/µc Si:H triple, and a Si:H/a Si:H/µc Si:H/µc Si:H quadruple junction solar cells. The solar cells were optimized in terms of photovoltage and photocurrent by varying the process parameters and thickness of the intrinsic absorber layers and by integrating microcrystalline silicon oxide as intermediate reflecting layers to adjust the photocurrents of the individual subcells. It was found that the electronic properties of the individual series-connected subcells can be adjusted to systematically tune the VOC between 1.9 V and 2.8 V and we achieved PV efficiencies over 11.5% for tandem and over 13.5% for triple and quadruple cells.
536 _ _ |a 126 - Solar Fuels (POF3-126)
|0 G:(DE-HGF)POF3-126
|c POF3-126
|x 0
|f POF III
536 _ _ |a 121 - Solar cells of the next generation (POF3-121)
|0 G:(DE-HGF)POF3-121
|c POF3-121
|x 1
|f POF III
536 _ _ |0 G:(DE-Juel1)HITEC-20170406
|x 2
|c HITEC-20170406
|a HITEC - Helmholtz Interdisciplinary Doctoral Training in Energy and Climate Research (HITEC) (HITEC-20170406)
700 1 _ |a Smirnov, Vladimir
|0 P:(DE-Juel1)130297
|b 1
|u fzj
700 1 _ |a Becker, Jan Philipp
|0 P:(DE-Juel1)142337
|b 2
|u fzj
700 1 _ |a Lambertz, Andreas
|0 P:(DE-Juel1)130263
|b 3
|u fzj
700 1 _ |a Rau, Uwe
|0 P:(DE-Juel1)143905
|b 4
|u fzj
700 1 _ |a Finger, Friedhelm
|0 P:(DE-Juel1)130238
|b 5
|u fzj
773 _ _ |y 2015
909 C O |o oai:juser.fz-juelich.de:200801
|p VDB
910 1 _ |a Forschungszentrum Jülich GmbH
|0 I:(DE-588b)5008462-8
|k FZJ
|b 0
|6 P:(DE-Juel1)156469
910 1 _ |a Forschungszentrum Jülich GmbH
|0 I:(DE-588b)5008462-8
|k FZJ
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910 1 _ |a Forschungszentrum Jülich GmbH
|0 I:(DE-588b)5008462-8
|k FZJ
|b 2
|6 P:(DE-Juel1)142337
910 1 _ |a Forschungszentrum Jülich GmbH
|0 I:(DE-588b)5008462-8
|k FZJ
|b 3
|6 P:(DE-Juel1)130263
910 1 _ |a Forschungszentrum Jülich GmbH
|0 I:(DE-588b)5008462-8
|k FZJ
|b 4
|6 P:(DE-Juel1)143905
910 1 _ |a Forschungszentrum Jülich GmbH
|0 I:(DE-588b)5008462-8
|k FZJ
|b 5
|6 P:(DE-Juel1)130238
913 0 _ |a DE-HGF
|b Energie
|l Erneuerbare Energien
|1 G:(DE-HGF)POF2-110
|0 G:(DE-HGF)POF2-111
|2 G:(DE-HGF)POF2-100
|v Thin Film Photovoltaics
|x 0
913 1 _ |a DE-HGF
|l Erneuerbare Energien
|1 G:(DE-HGF)POF3-120
|0 G:(DE-HGF)POF3-126
|2 G:(DE-HGF)POF3-100
|v Solar Fuels
|x 0
|4 G:(DE-HGF)POF
|3 G:(DE-HGF)POF3
|b Energie
913 1 _ |a DE-HGF
|l Erneuerbare Energien
|1 G:(DE-HGF)POF3-120
|0 G:(DE-HGF)POF3-121
|2 G:(DE-HGF)POF3-100
|v Solar cells of the next generation
|x 1
|4 G:(DE-HGF)POF
|3 G:(DE-HGF)POF3
|b Energie
914 1 _ |y 2015
920 1 _ |0 I:(DE-Juel1)IEK-5-20101013
|k IEK-5
|l Photovoltaik
|x 0
980 _ _ |a conf
980 _ _ |a VDB
980 _ _ |a I:(DE-Juel1)IEK-5-20101013
980 _ _ |a UNRESTRICTED
981 _ _ |a I:(DE-Juel1)IMD-3-20101013


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