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@INPROCEEDINGS{Richter:200860,
author = {Richter, Alexei and Zhao, Lei and Finger, Friedhelm and
Ding, Kaining},
title = {{N}ano-{C}omposite {M}icrostructure {M}odel for the
{C}lassification of {H}ydrogenated {N}anocrystalline
{S}ilicon {O}xide {T}hin-{F}ilms},
reportid = {FZJ-2015-03233},
year = {2015},
abstract = {A straightforward approach to increase the solar energy
conversion efficiency in solar cells is to reduce their
optical loss while maintaining the electrical performance.
For example, nanocrystalline hydrogenated silicon oxide
(nc-SiOx:H) can be implemented in silicon based solar cells
as a wide optical band gap material to diminish parasitic
optical losses. At the same time, an excellent electrical
conductivity can be achieved due to its unique
microstructure. In the present work, we introduce a
microstructure model that consistently correlates the
nc-SiOx:H microstructure to the deposition conditions during
Plasma Enhanced Chemical Vapour Deposition (PECVD) as well
as to the optoelectronic properties of nc-SiOx:H thin films.
We successfully validated the model by means of a large
quantity of systematically and individually optimized n- and
p-doped nc-SiOx:H films deposited at very high frequency
(VHF) and radio frequency (RF). In particular, this model
shows that the improved optoelectronic performance of
nc-SiOx:H films deposited at VHF as compared to RF might be
a consequence of an improved phase separation between the
conductive nanocrystalline silicon and the oxygen rich
matrix at VHF, which in turn is likely due to a higher
hydrogen radical density in the plasma as compared to RF. In
addition, we present our latest results on silicon thin-film
and silicon heterojunction solar cells using our newly
developed VHF nc-SiOx:H with superior optoelectronic
properties.},
month = {May},
date = {2015-05-11},
organization = {The 2015 Spring Conference of the
European Materials Research Society,
Lille (France), 11 May 2015 - 15 May
2015},
subtyp = {Other},
cin = {IEK-5},
cid = {I:(DE-Juel1)IEK-5-20101013},
pnm = {121 - Solar cells of the next generation (POF3-121) / HITEC
- Helmholtz Interdisciplinary Doctoral Training in Energy
and Climate Research (HITEC) (HITEC-20170406)},
pid = {G:(DE-HGF)POF3-121 / G:(DE-Juel1)HITEC-20170406},
typ = {PUB:(DE-HGF)6},
url = {https://juser.fz-juelich.de/record/200860},
}