%0 Journal Article
%A Adonin, Sergey A.
%A Izarova, Natalya V.
%A Besson, Claire
%A Abramov, Pavel A.
%A Santiago-Schübel, Beatrix
%A Kögerler, Paul
%A Fedin, Vladimir P.
%A Sokolov, Maxim N.
%T An Ir IV -containing polyoxometalate
%J Chemical communications
%V 51
%N 7
%@ 1364-548X
%C Cambridge
%I Soc.
%M FZJ-2015-03306
%P 1222 - 1225
%D 2015
%X [HIrIVW6O24]7−, representing the first Ir-containing Anderson–Evans-type polyanion and the first structurally characterized IrIV-based polyoxometalate, has been isolated as its hydrated sodium salt and characterized by single-crystal X-ray diffraction, mass spectrometry, and IR, UV-Vis and EPR spectroscopy. Cyclic voltammetry indicates that the IrIV ions in [HIrW6O24]7− can undergo reversible one-electron reduction and oxidation, resulting in IrIII and IrV derivatives.
%F PUB:(DE-HGF)16
%9 Journal Article
%U <Go to ISI:>//WOS:000346897300009
%$ pmid:25469664
%R 10.1039/C4CC09271F
%U https://juser.fz-juelich.de/record/200986