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000200986 1001_ $$0P:(DE-HGF)0$$aAdonin, Sergey A.$$b0
000200986 245__ $$aAn Ir IV -containing polyoxometalate
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000200986 520__ $$a[HIrIVW6O24]7−, representing the first Ir-containing Anderson–Evans-type polyanion and the first structurally characterized IrIV-based polyoxometalate, has been isolated as its hydrated sodium salt and characterized by single-crystal X-ray diffraction, mass spectrometry, and IR, UV-Vis and EPR spectroscopy. Cyclic voltammetry indicates that the IrIV ions in [HIrW6O24]7− can undergo reversible one-electron reduction and oxidation, resulting in IrIII and IrV derivatives.
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000200986 7001_ $$0P:(DE-HGF)0$$aIzarova, Natalya V.$$b1
000200986 7001_ $$0P:(DE-Juel1)140288$$aBesson, Claire$$b2
000200986 7001_ $$0P:(DE-HGF)0$$aAbramov, Pavel A.$$b3
000200986 7001_ $$0P:(DE-Juel1)133853$$aSantiago-Schübel, Beatrix$$b4
000200986 7001_ $$0P:(DE-Juel1)130782$$aKögerler, Paul$$b5$$eCorresponding Author$$ufzj
000200986 7001_ $$0P:(DE-HGF)0$$aFedin, Vladimir P.$$b6
000200986 7001_ $$0P:(DE-HGF)0$$aSokolov, Maxim N.$$b7
000200986 773__ $$0PERI:(DE-600)1472881-3$$a10.1039/C4CC09271F$$gVol. 51, no. 7, p. 1222 - 1225$$n7$$p1222 - 1225$$tChemical communications$$v51$$x1364-548X$$y2015
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