TY  - JOUR
AU  - Adonin, Sergey A.
AU  - Izarova, Natalya V.
AU  - Besson, Claire
AU  - Abramov, Pavel A.
AU  - Santiago-Schübel, Beatrix
AU  - Kögerler, Paul
AU  - Fedin, Vladimir P.
AU  - Sokolov, Maxim N.
TI  - An Ir IV -containing polyoxometalate
JO  - Chemical communications
VL  - 51
IS  - 7
SN  - 1364-548X
CY  - Cambridge
PB  - Soc.
M1  - FZJ-2015-03306
SP  - 1222 - 1225
PY  - 2015
AB  - [HIrIVW6O24]7−, representing the first Ir-containing Anderson–Evans-type polyanion and the first structurally characterized IrIV-based polyoxometalate, has been isolated as its hydrated sodium salt and characterized by single-crystal X-ray diffraction, mass spectrometry, and IR, UV-Vis and EPR spectroscopy. Cyclic voltammetry indicates that the IrIV ions in [HIrW6O24]7− can undergo reversible one-electron reduction and oxidation, resulting in IrIII and IrV derivatives.
LB  - PUB:(DE-HGF)16
UR  - <Go to ISI:>//WOS:000346897300009
C6  - pmid:25469664
DO  - DOI:10.1039/C4CC09271F
UR  - https://juser.fz-juelich.de/record/200986
ER  -