001     200986
005     20210129215600.0
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082 _ _ |a 540
100 1 _ |a Adonin, Sergey A.
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245 _ _ |a An Ir IV -containing polyoxometalate
260 _ _ |a Cambridge
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520 _ _ |a [HIrIVW6O24]7−, representing the first Ir-containing Anderson–Evans-type polyanion and the first structurally characterized IrIV-based polyoxometalate, has been isolated as its hydrated sodium salt and characterized by single-crystal X-ray diffraction, mass spectrometry, and IR, UV-Vis and EPR spectroscopy. Cyclic voltammetry indicates that the IrIV ions in [HIrW6O24]7− can undergo reversible one-electron reduction and oxidation, resulting in IrIII and IrV derivatives.
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700 1 _ |a Izarova, Natalya V.
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700 1 _ |a Besson, Claire
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700 1 _ |a Abramov, Pavel A.
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700 1 _ |a Santiago-Schübel, Beatrix
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700 1 _ |a Kögerler, Paul
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700 1 _ |a Fedin, Vladimir P.
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700 1 _ |a Sokolov, Maxim N.
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773 _ _ |a 10.1039/C4CC09271F
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