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000201035 0247_ $$2doi$$a10.1039/c3cp00049d
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000201035 0247_ $$2ISSN$$a1463-9084
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000201035 1001_ $$0P:(DE-Juel1)156589$$aSchwarz, Daniel$$b0$$eCorresponding Author
000201035 245__ $$aFormation and decay of a compressed phase of 4,4′-biphenyldicarboxylic acid on Cu(001)
000201035 260__ $$aCambridge$$bRSC Publ.$$c2013
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000201035 520__ $$aThe molecular arrangement of 4,4′-biphenyldicarboxylic acid (BDA) on Cu(001) has been studied at high coverage and relatively high temperature ([similar]400 K) using Low Energy Electron Microscopy, LEEM, and selected area diffraction, μLEED. Next to the previously reported c(8 × 8) structure, we also observe a compressed phase with a Image ID:c3cp00049d-t1.gif superstructure in matrix notation. All four equivalent (rotational and mirror) domains are equally populated. Both the c(8 × 8) and the compressed phase are confined to the first layer and the latter has a 14% higher density compared to the c(8 × 8) phase. Remarkably, this compressed phase is stable only during deposition and decays after interruption of the deposition. Apparently, the density of physisorbed admolecules on top of the c(8 × 8) layer has to be above a relevant threshold to allow the formation of the compressed phase.
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000201035 7001_ $$0P:(DE-HGF)0$$avan Gastel, Raoul$$b1
000201035 7001_ $$0P:(DE-HGF)0$$aZandvliet, Harold J. W.$$b2
000201035 7001_ $$0P:(DE-HGF)0$$aPoelsema, Bene$$b3
000201035 773__ $$0PERI:(DE-600)1476244-4$$a10.1039/c3cp00049d$$gVol. 15, no. 14, p. 5007 -$$n14$$p 5007-5016$$tPhysical chemistry, chemical physics$$v15$$x1463-9084$$y2013
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