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001     201035
005     20210129215610.0
024 7 _ |a 10.1039/c3cp00049d
|2 doi
024 7 _ |a 1463-9076
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024 7 _ |a 1463-9084
|2 ISSN
024 7 _ |a WOS:000316007900020
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037 _ _ |a FZJ-2015-03345
082 _ _ |a 540
100 1 _ |a Schwarz, Daniel
|0 P:(DE-Juel1)156589
|b 0
|e Corresponding Author
245 _ _ |a Formation and decay of a compressed phase of 4,4′-biphenyldicarboxylic acid on Cu(001)
260 _ _ |a Cambridge
|c 2013
|b RSC Publ.
336 7 _ |a Journal Article
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336 7 _ |a article
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520 _ _ |a The molecular arrangement of 4,4′-biphenyldicarboxylic acid (BDA) on Cu(001) has been studied at high coverage and relatively high temperature ([similar]400 K) using Low Energy Electron Microscopy, LEEM, and selected area diffraction, μLEED. Next to the previously reported c(8 × 8) structure, we also observe a compressed phase with a Image ID:c3cp00049d-t1.gif superstructure in matrix notation. All four equivalent (rotational and mirror) domains are equally populated. Both the c(8 × 8) and the compressed phase are confined to the first layer and the latter has a 14% higher density compared to the c(8 × 8) phase. Remarkably, this compressed phase is stable only during deposition and decays after interruption of the deposition. Apparently, the density of physisorbed admolecules on top of the c(8 × 8) layer has to be above a relevant threshold to allow the formation of the compressed phase.
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588 _ _ |a Dataset connected to CrossRef, juser.fz-juelich.de
700 1 _ |a van Gastel, Raoul
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700 1 _ |a Zandvliet, Harold J. W.
|0 P:(DE-HGF)0
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700 1 _ |a Poelsema, Bene
|0 P:(DE-HGF)0
|b 3
773 _ _ |a 10.1039/c3cp00049d
|g Vol. 15, no. 14, p. 5007 -
|0 PERI:(DE-600)1476244-4
|n 14
|p 5007-5016
|t Physical chemistry, chemical physics
|v 15
|y 2013
|x 1463-9084
909 C O |o oai:juser.fz-juelich.de:201035
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910 1 _ |a Forschungszentrum Jülich GmbH
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|b Forschungsbereich Energie
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