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024 7 _ |a 1744-6848
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100 1 _ |a Paul, N.
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245 _ _ |a Interfacial smoothening of polymer multilayers with molecules: a new approach in growing supramolecular layer structures
260 _ _ |a London
|c 2013
|b Royal Soc. of Chemistry
336 7 _ |a Journal Article
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520 _ _ |a The development of polymer-based structures is hindered due to the difficulties in realizing well-defined modulated structures without interpenetration of charged polymers. Two types of polyelectrolyte multilayer structures, with and without embedded layers of the biomolecule, glutamic acid, are compared using infrared spectroscopy and X-ray and neutron scattering techniques. Structure characterization of polyelectrolyte multilayers focuses usually on the arrangement along the surface normal. Using specular and off-specular neutron scattering we get insight into the in- and out-of-plane arrangement of the structure. A formation of well-defined, smooth layers is observed in the structure containing the biomolecule. This reduced roughness is associated with a drastic decrease in chain mobility responsible for interpenetration. In contrast, the multilayer without the biomolecule forms an island-like structure. Thus biomolecules can interrupt the propagation of island-like structures at such interfaces which can be effectively used in achieving well-defined supramolecular layer structures out of charged polymers.
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650 1 7 |a Polymers, Soft Nano Particles and Proteins
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693 _ _ |a Forschungs-Neutronenquelle Heinz Maier-Leibnitz
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700 1 _ |a Paul, A.
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700 1 _ |a Mattauch, S.
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700 1 _ |a Müller-Buschbaum, P.
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700 1 _ |a Böni, P.
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700 1 _ |a Lux-Steiner, M. Ch.
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773 _ _ |a 10.1039/c3sm51792f
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