guest ::
| Home > Publications database > Atomic and electronic structures of an extremely fragile liquid > print |
| Home > Publications database > Atomic and electronic structures of an extremely fragile liquid > print |
| 001 | 201509 | ||
| 005 | 20210129215811.0 | ||
| 024 | 7 | _ | |a 10.1038/ncomms6892 |2 doi |
| 024 | 7 | _ | |a 2128/8849 |2 Handle |
| 024 | 7 | _ | |a WOS:000347686900001 |2 WOS |
| 024 | 7 | _ | |a altmetric:2998347 |2 altmetric |
| 024 | 7 | _ | |a pmid:25520236 |2 pmid |
| 037 | _ | _ | |a FZJ-2015-03804 |
| 041 | _ | _ | |a English |
| 082 | _ | _ | |a 500 |
| 100 | 1 | _ | |a Kohara, Shinji |0 P:(DE-HGF)0 |b 0 |e Corresponding Author |
| 245 | _ | _ | |a Atomic and electronic structures of an extremely fragile liquid |
| 260 | _ | _ | |a London |c 2014 |b Nature Publishing Group |
| 336 | 7 | _ | |a Journal Article |b journal |m journal |0 PUB:(DE-HGF)16 |s 1435132655_21684 |2 PUB:(DE-HGF) |
| 336 | 7 | _ | |a Output Types/Journal article |2 DataCite |
| 336 | 7 | _ | |a Journal Article |0 0 |2 EndNote |
| 336 | 7 | _ | |a ARTICLE |2 BibTeX |
| 336 | 7 | _ | |a JOURNAL_ARTICLE |2 ORCID |
| 336 | 7 | _ | |a article |2 DRIVER |
| 520 | _ | _ | |a The structure of high-temperature liquids is an important topic for understanding the fragility of liquids. Here we report the structure of a high-temperature non-glass-forming oxide liquid, ZrO2, at an atomistic and electronic level. The Bhatia–Thornton number–number structure factor of ZrO2 does not show a first sharp diffraction peak. The atomic structure comprises ZrO5, ZrO6 and ZrO7 polyhedra with a significant contribution of edge sharing of oxygen in addition to corner sharing. The variety of large oxygen coordination and polyhedral connections with short Zr–O bond lifetimes, induced by the relatively large ionic radius of zirconium, disturbs the evolution of intermediate-range ordering, which leads to a reduced electronic band gap and increased delocalization in the ionic Zr–O bonding. The details of the chemical bonding explain the extremely low viscosity of the liquid and the absence of a first sharp diffraction peak, and indicate that liquid ZrO2 is an extremely fragile liquid. |
| 536 | _ | _ | |a 422 - Spin-based and quantum information (POF2-422) |0 G:(DE-HGF)POF2-422 |c POF2-422 |f POF II |x 0 |
| 588 | _ | _ | |a Dataset connected to CrossRef, juser.fz-juelich.de |
| 700 | 1 | _ | |a Akola, Jaakko |0 P:(DE-Juel1)130496 |b 1 |u fzj |
| 700 | 1 | _ | |a Patrikeev, Leonid |0 P:(DE-HGF)0 |b 2 |
| 700 | 1 | _ | |a Ropo, Matti |0 P:(DE-HGF)0 |b 3 |
| 700 | 1 | _ | |a Ohara, Koji |0 P:(DE-HGF)0 |b 4 |
| 700 | 1 | _ | |a Itou, Masayoshi |0 P:(DE-HGF)0 |b 5 |
| 700 | 1 | _ | |a Fujiwara, Akihiko |0 P:(DE-HGF)0 |b 6 |
| 700 | 1 | _ | |a Yahiro, Jumpei |0 P:(DE-HGF)0 |b 7 |
| 700 | 1 | _ | |a Okada, Junpei T. |0 P:(DE-HGF)0 |b 8 |
| 700 | 1 | _ | |a Ishikawa, Takehiko |0 P:(DE-HGF)0 |b 9 |
| 700 | 1 | _ | |a Mizuno, Akitoshi |0 P:(DE-HGF)0 |b 10 |
| 700 | 1 | _ | |a Masuno, Atsunobu |0 P:(DE-HGF)0 |b 11 |
| 700 | 1 | _ | |a Watanabe, Yasuhiro |0 P:(DE-HGF)0 |b 12 |
| 700 | 1 | _ | |a Usuki, Takeshi |0 P:(DE-HGF)0 |b 13 |
| 773 | _ | _ | |a 10.1038/ncomms6892 |g Vol. 5, p. 5892 - |0 PERI:(DE-600)2553671-0 |p 5892 |t Nature Communications |v 5 |y 2014 |x 2041-1723 |
| 856 | 4 | _ | |y OpenAccess |u https://juser.fz-juelich.de/record/201509/files/ncomms6892.pdf |
| 856 | 4 | _ | |y OpenAccess |x icon |u https://juser.fz-juelich.de/record/201509/files/ncomms6892.gif?subformat=icon |
| 856 | 4 | _ | |y OpenAccess |x icon-1440 |u https://juser.fz-juelich.de/record/201509/files/ncomms6892.jpg?subformat=icon-1440 |
| 856 | 4 | _ | |y OpenAccess |x icon-180 |u https://juser.fz-juelich.de/record/201509/files/ncomms6892.jpg?subformat=icon-180 |
| 856 | 4 | _ | |y OpenAccess |x icon-640 |u https://juser.fz-juelich.de/record/201509/files/ncomms6892.jpg?subformat=icon-640 |
| 856 | 4 | _ | |y OpenAccess |x pdfa |u https://juser.fz-juelich.de/record/201509/files/ncomms6892.pdf?subformat=pdfa |
| 909 | C | O | |o oai:juser.fz-juelich.de:201509 |p openaire |p open_access |p driver |p VDB |p dnbdelivery |
| 910 | 1 | _ | |a Forschungszentrum Jülich GmbH |0 I:(DE-588b)5008462-8 |k FZJ |b 1 |6 P:(DE-Juel1)130496 |
| 913 | 2 | _ | |a DE-HGF |b Forschungsbereich Energie |l Future Information Technology - Fundamentals, Novel Concepts and Energy Efficiency (FIT) |1 G:(DE-HGF)POF3-140 |0 G:(DE-HGF)POF3-142 |2 G:(DE-HGF)POF3-100 |v Controlling Spin-Based Phenomena |x 0 |
| 913 | 2 | _ | |a DE-HGF |b Forschungsbereich Energie |l Future Information Technology - Fundamentals, Novel Concepts and Energy Efficiency (FIT) |1 G:(DE-HGF)POF3-140 |0 G:(DE-HGF)POF3-143 |2 G:(DE-HGF)POF3-100 |v Controlling Configuration-Based Phenomena |x 1 |
| 913 | 1 | _ | |a DE-HGF |b Schlüsseltechnologien |1 G:(DE-HGF)POF2-420 |0 G:(DE-HGF)POF2-422 |2 G:(DE-HGF)POF2-400 |v Spin-based and quantum information |x 0 |4 G:(DE-HGF)POF |3 G:(DE-HGF)POF2 |l Grundlagen zukünftiger Informationstechnologien |
| 914 | 1 | _ | |y 2015 |
| 915 | _ | _ | |a Creative Commons Attribution CC BY 4.0 |0 LIC:(DE-HGF)CCBY4 |2 HGFVOC |
| 915 | _ | _ | |a JCR |0 StatID:(DE-HGF)0100 |2 StatID |
| 915 | _ | _ | |a WoS |0 StatID:(DE-HGF)0110 |2 StatID |b Science Citation Index |
| 915 | _ | _ | |a WoS |0 StatID:(DE-HGF)0111 |2 StatID |b Science Citation Index Expanded |
| 915 | _ | _ | |a DBCoverage |0 StatID:(DE-HGF)0150 |2 StatID |b Web of Science Core Collection |
| 915 | _ | _ | |a DBCoverage |0 StatID:(DE-HGF)0199 |2 StatID |b Thomson Reuters Master Journal List |
| 915 | _ | _ | |a DBCoverage |0 StatID:(DE-HGF)0200 |2 StatID |b SCOPUS |
| 915 | _ | _ | |a DBCoverage |0 StatID:(DE-HGF)0300 |2 StatID |b Medline |
| 915 | _ | _ | |a DBCoverage |0 StatID:(DE-HGF)0310 |2 StatID |b NCBI Molecular Biology Database |
| 915 | _ | _ | |a OpenAccess |0 StatID:(DE-HGF)0510 |2 StatID |
| 915 | _ | _ | |a DBCoverage |0 StatID:(DE-HGF)1030 |2 StatID |b Current Contents - Life Sciences |
| 915 | _ | _ | |a DBCoverage |0 StatID:(DE-HGF)1040 |2 StatID |b Zoological Record |
| 915 | _ | _ | |a DBCoverage |0 StatID:(DE-HGF)1050 |2 StatID |b BIOSIS Previews |
| 915 | _ | _ | |a DBCoverage |0 StatID:(DE-HGF)1060 |2 StatID |b Current Contents - Agriculture, Biology and Environmental Sciences |
| 915 | _ | _ | |a DBCoverage |0 StatID:(DE-HGF)1150 |2 StatID |b Current Contents - Physical, Chemical and Earth Sciences |
| 915 | _ | _ | |a IF >= 10 |0 StatID:(DE-HGF)9910 |2 StatID |
| 920 | 1 | _ | |0 I:(DE-Juel1)IAS-1-20090406 |k IAS-1 |l Quanten-Theorie der Materialien |x 0 |
| 920 | 1 | _ | |0 I:(DE-Juel1)PGI-1-20110106 |k PGI-1 |l Quanten-Theorie der Materialien |x 1 |
| 980 | _ | _ | |a journal |
| 980 | _ | _ | |a VDB |
| 980 | _ | _ | |a FullTexts |
| 980 | _ | _ | |a UNRESTRICTED |
| 980 | _ | _ | |a I:(DE-Juel1)IAS-1-20090406 |
| 980 | _ | _ | |a I:(DE-Juel1)PGI-1-20110106 |
| 980 | 1 | _ | |a FullTexts |
| 981 | _ | _ | |a I:(DE-Juel1)PGI-1-20110106 |
| Library | Collection | CLSMajor | CLSMinor | Language | Author |
|---|