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000201768 1001_ $$0P:(DE-HGF)0$$aStroppa, Daniel G.$$b0$$eCorresponding Author
000201768 245__ $$aAnalysis of Dopant Atom Distribution and Quantification of Oxygen Vacancies on Individual Gd-Doped CeO 2 Nanocrystals
000201768 260__ $$aWeinheim$$bWiley-VCH$$c2014
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000201768 520__ $$aThis work reports the analysis of the distribution of Gd atoms and the quantification of O vacancies applied to individual CeO2 and Gd-doped CeO2 nanocrystals by electron energy-loss spectroscopy. The concentration of O vacancies measured on the undoped system (6.3±2.6 %) matches the expected value given the typical Ce3+ content previously reported for CeO2 nanoparticles. The doped nanoparticles have an uneven distribution of dopant atoms and an atypical amount of O vacant sites (37.7±4.1 %). The measured decrease of the O content induced by Gd doping cannot be explained solely by the charge balance including Ce3+ and Gd3+ ions.
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000201768 7001_ $$0P:(DE-HGF)0$$aDalmaschio, Cleocir J.$$b1
000201768 7001_ $$0P:(DE-Juel1)130723$$aHouben, Lothar$$b2$$ufzj
000201768 7001_ $$0P:(DE-Juel1)130525$$aBarthel, Juri$$b3$$ufzj
000201768 7001_ $$0P:(DE-HGF)0$$aMontoro, Luciano A.$$b4
000201768 7001_ $$0P:(DE-HGF)0$$aLeite, Edson R.$$b5
000201768 7001_ $$0P:(DE-HGF)0$$aRamirez, Antonio J.$$b6
000201768 773__ $$0PERI:(DE-600)1478547-x$$a10.1002/chem.201400412$$gVol. 20, no. 21, p. 6288 - 6293$$n21$$p6288 - 6293$$tChemistry - a European journal$$v20$$x0947-6539$$y2014
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