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024 7 _ |a 10.1002/chem.201400412
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024 7 _ |a 1521-3765
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100 1 _ |a Stroppa, Daniel G.
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245 _ _ |a Analysis of Dopant Atom Distribution and Quantification of Oxygen Vacancies on Individual Gd-Doped CeO 2 Nanocrystals
260 _ _ |a Weinheim
|c 2014
|b Wiley-VCH
336 7 _ |a Journal Article
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520 _ _ |a This work reports the analysis of the distribution of Gd atoms and the quantification of O vacancies applied to individual CeO2 and Gd-doped CeO2 nanocrystals by electron energy-loss spectroscopy. The concentration of O vacancies measured on the undoped system (6.3±2.6 %) matches the expected value given the typical Ce3+ content previously reported for CeO2 nanoparticles. The doped nanoparticles have an uneven distribution of dopant atoms and an atypical amount of O vacant sites (37.7±4.1 %). The measured decrease of the O content induced by Gd doping cannot be explained solely by the charge balance including Ce3+ and Gd3+ ions.
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700 1 _ |a Dalmaschio, Cleocir J.
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700 1 _ |a Houben, Lothar
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700 1 _ |a Barthel, Juri
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700 1 _ |a Montoro, Luciano A.
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700 1 _ |a Leite, Edson R.
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700 1 _ |a Ramirez, Antonio J.
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773 _ _ |a 10.1002/chem.201400412
|g Vol. 20, no. 21, p. 6288 - 6293
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