Home > Publications database > Analysis of Dopant Atom Distribution and Quantification of Oxygen Vacancies on Individual Gd-Doped CeO 2 Nanocrystals > print |
001 | 201768 | ||
005 | 20240610115628.0 | ||
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100 | 1 | _ | |a Stroppa, Daniel G. |0 P:(DE-HGF)0 |b 0 |e Corresponding Author |
245 | _ | _ | |a Analysis of Dopant Atom Distribution and Quantification of Oxygen Vacancies on Individual Gd-Doped CeO 2 Nanocrystals |
260 | _ | _ | |a Weinheim |c 2014 |b Wiley-VCH |
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520 | _ | _ | |a This work reports the analysis of the distribution of Gd atoms and the quantification of O vacancies applied to individual CeO2 and Gd-doped CeO2 nanocrystals by electron energy-loss spectroscopy. The concentration of O vacancies measured on the undoped system (6.3±2.6 %) matches the expected value given the typical Ce3+ content previously reported for CeO2 nanoparticles. The doped nanoparticles have an uneven distribution of dopant atoms and an atypical amount of O vacant sites (37.7±4.1 %). The measured decrease of the O content induced by Gd doping cannot be explained solely by the charge balance including Ce3+ and Gd3+ ions. |
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700 | 1 | _ | |a Dalmaschio, Cleocir J. |0 P:(DE-HGF)0 |b 1 |
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700 | 1 | _ | |a Montoro, Luciano A. |0 P:(DE-HGF)0 |b 4 |
700 | 1 | _ | |a Leite, Edson R. |0 P:(DE-HGF)0 |b 5 |
700 | 1 | _ | |a Ramirez, Antonio J. |0 P:(DE-HGF)0 |b 6 |
773 | _ | _ | |a 10.1002/chem.201400412 |g Vol. 20, no. 21, p. 6288 - 6293 |0 PERI:(DE-600)1478547-x |n 21 |p 6288 - 6293 |t Chemistry - a European journal |v 20 |y 2014 |x 0947-6539 |
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