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@ARTICLE{BenMoshe:201769,
      author       = {Ben-Moshe, Assaf and Wolf, Sharon Grayer and Sadan, Maya
                      Bar and Houben, Lothar and Fan, Zhiyuan and Govorov,
                      Alexander O. and Markovich, Gil},
      title        = {{E}nantioselective control of lattice and shape chirality
                      in inorganic nanostructures using chiral biomolecules},
      journal      = {Nature Communications},
      volume       = {5},
      issn         = {2041-1723},
      address      = {London},
      publisher    = {Nature Publishing Group},
      reportid     = {FZJ-2015-04063},
      pages        = {4302},
      year         = {2014},
      abstract     = {A large number of inorganic materials form crystals with
                      chiral symmetry groups. Enantioselectively synthesizing
                      nanostructures of such materials should lead to interesting
                      optical activity effects. Here we report the synthesis of
                      colloidal tellurium and selenium nanostructures using
                      thiolated chiral biomolecules. The synthesis conditions are
                      tuned to obtain tellurium nanostructures with chiral shapes
                      and large optical activity. These nanostructures exhibit
                      visible optical and chiroptical responses that shift with
                      size and are successfully simulated by an electromagnetic
                      model. The model shows that they behave as chiral optical
                      resonators. The chiral tellurium nanostructures are
                      transformed into chiral gold and silver telluride
                      nanostructures with very large chiroptical activity,
                      demonstrating a simple colloidal chemistry path to chiral
                      plasmonic and semiconductor metamaterials. These materials
                      are natural candidates for studies related to interactions
                      of chiral (bio)molecules with chiral inorganic surfaces,
                      with relevance to asymmetric catalysis, chiral
                      crystallization and the evolution of homochirality in
                      biomolecules.},
      cin          = {PGI-5},
      ddc          = {500},
      cid          = {I:(DE-Juel1)PGI-5-20110106},
      pnm          = {42G - Peter Grünberg-Centre (PG-C) (POF2-42G41)},
      pid          = {G:(DE-HGF)POF2-42G41},
      typ          = {PUB:(DE-HGF)16},
      UT           = {WOS:000340613800010},
      doi          = {10.1038/ncomms5302},
      url          = {https://juser.fz-juelich.de/record/201769},
}