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001     201805
005     20210129215920.0
024 7 _ |a 10.1103/PhysRevLett.108.036102
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024 7 _ |a 1079-7114
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024 7 _ |a 2128/8864
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100 1 _ |a Sivebaek, I. M.
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245 _ _ |a Effective Viscosity of Confined Hydrocarbons
260 _ _ |a College Park, Md.
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520 _ _ |a We present molecular dynamics friction calculations for confined hydrocarbon films with molecular lengths from 20 to 1400 carbon atoms. We find that the logarithm of the effective viscosity ηeff for nanometer-thin films depends linearly on the logarithm of the shear rate: logηeff=C−nlogγ˙, where n varies from 1 (solidlike friction) at very low temperatures to 0 (Newtonian liquid) at very high temperatures, following an inverse sigmoidal curve. Only the shortest chain molecules melt, whereas the longer ones only show a softening in the studied temperature interval 0
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700 1 _ |a Samoilov, V. N.
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700 1 _ |a Persson, Bo
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773 _ _ |a 10.1103/PhysRevLett.108.036102
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