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@ARTICLE{Mishra:20184,
author = {Mishra, S.K. and Mittal, R. and Chaplot, S. L. and
Ovsyannikov, S.V. and Trots, D.M. and Dubrovinsky, L. and
Su, Y. and Brückel, T. and Matsuishi, S. and Hosono, H. and
Garbarino, G.},
title = {{P}ressure dependence of the low-temperature crystal
structure and phase transition behavior of {C}a{F}e{A}s{F}
and {S}r{F}e{A}s{F}: {A} synchrotron x-ray diffraction
study},
journal = {Physical review / B},
volume = {84},
number = {22},
issn = {1098-0121},
address = {College Park, Md.},
publisher = {APS},
reportid = {PreJuSER-20184},
pages = {224513},
year = {2011},
note = {R. Mittal and S. K. Mishra thank the Department of Science
and Technology (DST), India for providing financial support
to carry out synchrotron x-ray diffraction at the European
Synchrotron Radiation Facility, Grenoble, France.},
abstract = {We report systematic investigation of high pressure crystal
structures and structural phase transition up to 46 GPa in
CaFeAsF and 40 GPa in SrFeAsF at 40 K using powder
synchrotron x-ray diffraction experiments and Rietveld
analysis of the diffraction data. We find that CaFeAsF
undergoes orthorhombic to monoclinic phase transition at P-c
= 13.7 GPa while increasing pressure. SrFeAsF exhibits
coexistence of orthorhombic and monoclinic phases over a
large pressure range from 9 to 39 GPa. The coexistence of
the two phases indicates that the transition is of first
order in nature. Unlike in the 122 compounds (BaFe2As2 and
CaFe2As2), we do not find any collapse tetragonal
transition. The transition to a lower symmetry phase
(orthorhombic to monoclinic) in 1111 compounds under
pressure is in contrast with the transition to a high
symmetry phase (orthorhombic to tetragonal) in 122-type
compounds. On heating from 40 K at high pressure, CaFeAsF
undergoes monoclinic to tetragonal phase transition around
25 GPa and 200 K. Further, it does not show any
post-tetragonal phase transition and remains in the
tetragonal phase up to 25 GPa at 300 K. The dP(c)/dT is
found to be positive for the CaFeAsF and CaFe2As2, however
the same was not found in case of BaFe2As2.},
keywords = {J (WoSType)},
cin = {PGI-4 / JARA-FIT / JCNS (München) ; Jülich Centre for
Neutron Science JCNS (München) ; JCNS-FRM-II / JCNS-2},
ddc = {530},
cid = {I:(DE-Juel1)PGI-4-20110106 / $I:(DE-82)080009_20140620$ /
I:(DE-Juel1)JCNS-FRM-II-20110218 /
I:(DE-Juel1)JCNS-2-20110106},
pnm = {Grundlagen für zukünftige Informationstechnologien /
Großgeräte für die Forschung mit Photonen, Neutronen und
Ionen (PNI)},
pid = {G:(DE-Juel1)FUEK412 / G:(DE-Juel1)FUEK415},
experiment = {EXP:(DE-MLZ)NOSPEC-20140101},
shelfmark = {Physics, Condensed Matter},
typ = {PUB:(DE-HGF)16},
UT = {WOS:000298555800011},
doi = {10.1103/PhysRevB.84.224513},
url = {https://juser.fz-juelich.de/record/20184},
}