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@ARTICLE{Nemk:201869,
author = {Nemšák, Slavomír and Shavorskiy, Andrey and Karslioglu,
Osman and Zegkinoglou, Ioannis and Rattanachata, Arunothai
and Conlon, Catherine S. and Keqi, Armela and Greene, Peter
K. and Burks, Edward C. and Salmassi, Farhad and Gullikson,
Eric M. and Yang, See-Hun and Liu, Kai and Bluhm, Hendrik
and Fadley, Charles S.},
title = {{C}oncentration and chemical-state profiles at
heterogeneous interfaces with sub-nm accuracy from
standing-wave ambient-pressure photoemission},
journal = {Nature Communications},
volume = {5},
issn = {2041-1723},
address = {London},
publisher = {Nature Publishing Group},
reportid = {FZJ-2015-04163},
pages = {5441 -},
year = {2014},
abstract = {Heterogeneous processes at solid/gas, liquid/gas and
solid/liquid interfaces are ubiquitous in modern devices and
technologies but often difficult to study quantitatively.
Full characterization requires measuring the depth profiles
of chemical composition and state with enhanced sensitivity
to narrow interfacial regions of a few to several nm in
extent over those originating from the bulk phases on either
side of the interface. We show for a model system of NaOH
and CsOH in an ~1-nm thick hydrated layer on α-Fe2O3
(haematite) that combining ambient-pressure X-ray
photoelectron spectroscopy and standing-wave photoemission
spectroscopy provides the spatial arrangement of the bulk
and interface chemical species, as well as local potential
energy variations, along the direction perpendicular to the
interface with sub-nm accuracy. Standing-wave
ambient-pressure photoemission spectroscopy is thus a very
promising technique for measuring such important interfaces,
with relevance to energy research, heterogeneous catalysis,
electrochemistry, and atmospheric and environmental
science.},
cin = {PGI-6},
ddc = {500},
cid = {I:(DE-Juel1)PGI-6-20110106},
pnm = {422 - Spin-based and quantum information (POF2-422)},
pid = {G:(DE-HGF)POF2-422},
typ = {PUB:(DE-HGF)16},
UT = {WOS:000345908900001},
pubmed = {pmid:25399688},
doi = {10.1038/ncomms6441},
url = {https://juser.fz-juelich.de/record/201869},
}