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@ARTICLE{Pilch:201902,
author = {Pilch, M. and Molak, A. and Szot, K.},
title = {{T}hermal {T}reatment {E}ffects in {P}b{T}i{O} $_{3}$
{C}rystals {S}tudied by {XPS} and {E}lectric {C}onductivity
{T}ests},
journal = {Ferroelectrics},
volume = {466},
number = {1},
issn = {1563-5112},
address = {London [u.a.]},
publisher = {Taylor $\&$ Francis},
reportid = {FZJ-2015-04192},
pages = {51 - 62},
year = {2014},
abstract = {The as-grown aged and thermally annealed at 720 K and 820 K
PbTiO3 crystals were prepared. The ɛ′(T,f) and σAC(T,f)
were measured at radio frequencies. Samples heated at 720 K
shown resistive switching to metallic-type σAC(T). The
resistivity switching was confirmed by RDC(T) measurement.
The samples annealed at 820 K were rejuvenated, exhibited
Curie-Weiss dependence above TC = 750 K and semiconductor
conductivity. Annealing induced changes in shape of the Pb
4f, Ti 2p, O 1s, and VB XPS lines. We propose a model
related to ionic migration toward FE domain walls and to
vortices which provide conducting channels.},
cin = {PGI-7},
ddc = {530},
cid = {I:(DE-Juel1)PGI-7-20110106},
pnm = {421 - Frontiers of charge based Electronics (POF2-421)},
pid = {G:(DE-HGF)POF2-421},
typ = {PUB:(DE-HGF)16},
UT = {WOS:000335946100008},
doi = {10.1080/00150193.2014.894866},
url = {https://juser.fz-juelich.de/record/201902},
}