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@ARTICLE{Nowak:201903,
author = {Nowak, A. and Persson, J. and Schmelzer, B. and Szade, J.
and Szot, K.},
title = {{L}ow temperature reduction in {T}a–{O} and {N}b–{O}
thin films},
journal = {Journal of physics / D},
volume = {47},
number = {13},
issn = {1361-6463},
address = {Bristol},
publisher = {IOP Publ.},
reportid = {FZJ-2015-04193},
pages = {135301 -},
year = {2014},
abstract = {The effect of thermal reduction in ultra-high vacuum was
studied in films of tantalum and niobium oxides obtained by
oxidation of deposited metallic layers. The obtained films
appeared to be amorphous and their stoichiometry was not
uniform. For the Ta based film the main component was Ta2O5
while for the oxidized Nb film the pentoxide was present in
the topmost part of the film and the thickest layer had the
electron density assigned to NbO2. Thermal reduction was
studied with the use of in situ photoelectron spectroscopy
which revealed for the Nb–O film a strong effect for
temperature as low as 300 °C. The Nb–O film reduced at
600 °C exhibited dominating metallic-like electronic states
assigned to NbO. For the Ta–O film the significant
reduction process started above 600 °C. At 900 °C the film
showed metallic-like states which can be attributed to Ta2O.
A single crystal of Nb2O5 showed no effect of reduction for
temperatures up to 500 °C. A test performed with the use of
local conductivity atomic force microscopy showed the most
interesting bipolar-like resistive switching properties for
the films reduced at temperatures up to 300 °C.},
cin = {PGI-4 / PGI-7},
ddc = {530},
cid = {I:(DE-Juel1)PGI-4-20110106 / I:(DE-Juel1)PGI-7-20110106},
pnm = {421 - Frontiers of charge based Electronics (POF2-421)},
pid = {G:(DE-HGF)POF2-421},
typ = {PUB:(DE-HGF)16},
UT = {WOS:000332791200011},
doi = {10.1088/0022-3727/47/13/135301},
url = {https://juser.fz-juelich.de/record/201903},
}