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@ARTICLE{Sergueev:202012,
author = {Sergueev, I. and Glazyrin, K. and Kantor, I. and McGuire,
M. A. and Chumakov, A. I. and Klobes, B. and Sales, B. C.
and Hermann, Raphael},
title = {{Q}uenching rattling modes in skutterudites with pressure},
journal = {Physical review / B},
volume = {91},
number = {22},
issn = {1098-0121},
address = {College Park, Md.},
publisher = {APS},
reportid = {FZJ-2015-04301},
pages = {224304},
year = {2015},
abstract = {A high-pressure study of the lattice dynamics in the filled
skutterudite Eu0.84Fe4Sb12 was carried out by means of x-ray
powder diffraction and nuclear inelastic scattering. The
anharmonicity of particular phonon modes was characterized
by mode and element specific Grüneisen parameters. The
large anharmonicity of the rattling optical mode that is
hybridized with the acoustical phonons at ambient pressure
is reduced at high pressure as the phonon modes decouple.
This result suggests that anharmonic coupling between
acoustic and optical phonon modes plays a central role in
the reduced thermal conductivity.},
cin = {JCNS-2 / PGI-4 / JARA-FIT},
ddc = {530},
cid = {I:(DE-Juel1)JCNS-2-20110106 / I:(DE-Juel1)PGI-4-20110106 /
$I:(DE-82)080009_20140620$},
pnm = {144 - Controlling Collective States (POF3-144) / 542 -
Hybrid and Functionalised Structures (POF3-542) / 6213 -
Materials and Processes for Energy and Transport
Technologies (POF3-621) / 6G4 - Jülich Centre for Neutron
Research (JCNS) (POF3-623)},
pid = {G:(DE-HGF)POF3-144 / G:(DE-HGF)POF3-542 /
G:(DE-HGF)POF3-6213 / G:(DE-HGF)POF3-6G4},
typ = {PUB:(DE-HGF)16},
UT = {WOS:000356129600006},
doi = {10.1103/PhysRevB.91.224304},
url = {https://juser.fz-juelich.de/record/202012},
}