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@ARTICLE{Xiao:202214,
      author       = {Xiao, Bin and Klinkenberg, Martina and Bosbach, Dirk and
                      Suleimanov, Evgeny V. and Alekseev, Evgeny},
      title        = {{E}ffects of {T}e({IV}) {O}xo-{A}nion {I}ncorporation into
                      {T}horium {M}olybdates and {T}ungstates},
      journal      = {Inorganic chemistry},
      volume       = {54},
      number       = {12},
      issn         = {1520-510X},
      address      = {Washington, DC},
      publisher    = {American Chemical Society},
      reportid     = {FZJ-2015-04503},
      pages        = {5981 - 5990},
      year         = {2015},
      abstract     = {The exploration of phase formation in the Th−Mo/W−Te
                      systems has resulted in four mixed oxo-anion compounds from
                      high-temperature solid-state reactions:ThWTe2O9,
                      Th(WO4)(TeO3), ThMoTe2O9, and Th2(MoO4)-(TeO3)3. All four
                      compounds contain edge-sharing thorium polyhedra linked by
                      MoO4/WO6 and different tellurium oxogroups to form
                      three-dimensional frameworks. In ThWTe2O9, each helical Th
                      based chain is connected by four tungstotellurite clusters
                      resulting in a building fragment which has a crosssection of
                      four-leafed clovers. The structure of Th(WO4)(TeO3) exhibits
                      a multilayer-sandwich framework composed of thorium
                      tellurite layers with tungsten chains in between. In the
                      case of the molybdate family, ThMoTe2O9 and Th2(MoO4)(TeO3)3
                      are built from puckered Th−Te sheets which are further
                      interconnected by MoO4 tetrahedral linkers. The DSC-TG
                      technique was performed to gain insight into the thermal
                      behavior of the synthesized compounds. Raman spectra of
                      as-prepared phases were obtained and analyzed for signature
                      peaks.},
      cin          = {IEK-6},
      ddc          = {540},
      cid          = {I:(DE-Juel1)IEK-6-20101013},
      pnm          = {161 - Nuclear Waste Management (POF3-161) / Helmholtz Young
                      Investigators Group: Energy (HGF-YIG-Energy) / HITEC -
                      Helmholtz Interdisciplinary Doctoral Training in Energy and
                      Climate Research (HITEC) (HITEC-20170406)},
      pid          = {G:(DE-HGF)POF3-161 / G:(DE-HGF)HGF-YIG-Energy /
                      G:(DE-Juel1)HITEC-20170406},
      typ          = {PUB:(DE-HGF)16},
      UT           = {WOS:000356467100039},
      pubmed       = {pmid:26020835},
      doi          = {10.1021/acs.inorgchem.5b00789},
      url          = {https://juser.fz-juelich.de/record/202214},
}