% IMPORTANT: The following is UTF-8 encoded.  This means that in the presence
% of non-ASCII characters, it will not work with BibTeX 0.99 or older.
% Instead, you should use an up-to-date BibTeX implementation like “bibtex8” or
% “biber”.

@ARTICLE{Wandt:202229,
      author       = {Wandt, Johannes and Marino, Cyril and Gasteiger, Hubert A.
                      and Jakes, Peter and Eichel, Rüdiger-A. and Granwehr,
                      Josef},
      title        = {{O}perando electron paramagnetic resonance spectroscopy –
                      formation of mossy lithium on lithium anodes during
                      charge–discharge cycling},
      journal      = {Energy $\&$ environmental science},
      volume       = {8},
      number       = {4},
      issn         = {1754-5706},
      address      = {Cambridge},
      publisher    = {RSC Publ.},
      reportid     = {FZJ-2015-04518},
      pages        = {1358 - 1367},
      year         = {2015},
      abstract     = {The formation of mossy lithium and lithium dendrites so far
                      prevents the use of lithium metal anodes in lithium ion
                      batteries. To develop solutions for this problem (e.g.,
                      electrolyte additives), operando measurement techniques are
                      required to monitor mossy lithium and dendrite formation
                      during electrochemical cycling. Here we present a novel
                      battery cell design that enables operando electron
                      paramagnetic resonance (EPR) spectroscopy. It is shown that
                      time-resolved operando EPR spectroscopy during
                      electrochemical cycling of a lithium-metal/LiFePO4 (LFP)
                      cell provides unique insights into the lithium
                      plating/dissolution mechanisms, which are consistent with ex
                      situ scanning electron microscopy (SEM) analysis. To
                      demonstrate the viability of the operando EPR method, two
                      cells using different electrolytes were studied. When using
                      an electrolyte containing fluoroethylene carbonate (FEC)
                      additive, a higher reversibility of the lithium anode and
                      reduced formation of micro-structured (mossy/dendritic)
                      lithium were observed.},
      cin          = {IEK-9},
      ddc          = {690},
      cid          = {I:(DE-Juel1)IEK-9-20110218},
      pnm          = {131 - Electrochemical Storage (POF3-131)},
      pid          = {G:(DE-HGF)POF3-131},
      typ          = {PUB:(DE-HGF)16},
      UT           = {WOS:000352275500024},
      doi          = {10.1039/C4EE02730B},
      url          = {https://juser.fz-juelich.de/record/202229},
}