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@ARTICLE{Arnebold:202350,
      author       = {Arnebold, A. and Thiel, K. and Kentzinger, E. and Hartwig,
                      A.},
      title        = {{M}orphological adjustment determines the properties of
                      cationically polymerized epoxy resins},
      journal      = {RSC Advances},
      volume       = {5},
      number       = {53},
      issn         = {2046-2069},
      address      = {London},
      publisher    = {RSC Publishing},
      reportid     = {FZJ-2015-04612},
      pages        = {42482 - 42491},
      year         = {2015},
      abstract     = {The morphological adjustment of a cationically polymerized
                      cycloaliphatic epoxy resin is presented. For this purpose,
                      the epoxy resin is polymerized both with a reactive
                      poly(ε-caprolactone) (PCL-diol) and a unreactive one
                      (PCL-diester) leading to a copolymer and a polymer alloy of
                      different morphologies, respectively. Small-angle X-ray
                      scattering (SAXS) shows that the formed nanostructures are
                      the result of the reaction-induced microphase separation
                      (RIMS) mechanism. The activated monomer mechanism (AM)
                      proceeded faster than the activated chain end mechanism
                      (ACE) leading to a preferred integration of PCL-diol into
                      the epoxy network so that segregation is partially
                      inhibited, especially for small polyester contents. It was
                      shown that esterified PCL did not react with the epoxy resin
                      so that it was forced to segregate greatly in the form of
                      spherulitic domains. This was shown by STEM imaging, by the
                      occurrence of crystallinity, as well as by enhanced glass
                      transition temperatures compared to its comparable
                      copolymers.},
      cin          = {JCNS-2 / PGI-4 / JARA-FIT},
      ddc          = {540},
      cid          = {I:(DE-Juel1)JCNS-2-20110106 / I:(DE-Juel1)PGI-4-20110106 /
                      $I:(DE-82)080009_20140620$},
      pnm          = {144 - Controlling Collective States (POF3-144) / 524 -
                      Controlling Collective States (POF3-524) / 6213 - Materials
                      and Processes for Energy and Transport Technologies
                      (POF3-621) / 6G4 - Jülich Centre for Neutron Research
                      (JCNS) (POF3-623)},
      pid          = {G:(DE-HGF)POF3-144 / G:(DE-HGF)POF3-524 /
                      G:(DE-HGF)POF3-6213 / G:(DE-HGF)POF3-6G4},
      typ          = {PUB:(DE-HGF)16},
      UT           = {WOS:000354447800034},
      doi          = {10.1039/C5RA03042K},
      url          = {https://juser.fz-juelich.de/record/202350},
}