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@PHDTHESIS{Lehnen:202687,
author = {Lehnen, Stephan},
title = {{I}nvestigation of light propagation in thin-film silicon
solar cells by dual-probe scanning near-field optical
microscopy},
volume = {270},
school = {RWTH Aachen},
type = {Dr.},
address = {Jülich},
publisher = {Forschungszentrum Jülich GmbH Zentralbibliothek, Verlag},
reportid = {FZJ-2015-04871},
isbn = {978-3-95806-066-1},
series = {Schriften des Forschungszentrums Jülich Reihe Energie $\&$
Umwelt / Energy $\&$ Environment},
pages = {120 S.},
year = {2015},
note = {RWTH Aachen, Diss., 2015},
abstract = {In this work, the light propagation in microcrystalline
silicon thin film solar cells is investigated. For this
purpose, a dual-probe scanning near-field optical microscope
(SNOM) wasdeveloped and set up from scratch. The microscope
is equiped with two separated probes for local illumination
and detection on a subwavelength scale. Applying newly
developed modes of measurement, exclusively available at
dual probe SNOMs, the microscope allows for measuring the
propagation of light in thin layers with high precision.
Within the framework of this thesis, the different physical
challenges of dual probe scanning near-field optical
microscopy are outlined and the technological solutions are
described. The reliability of the setup was thoroughly
tested at measurements of light propagation in flat and
textured microcrystalline silicon (μc-Si:H) thin film solar
cells in nip-configuration. The measured raw data are
analysed by multiple methods. It is observed, that the
lateral intensity decay of light is strongly influenced by
local surface features. Therefore, an advanced dual-probe
scan mode is introduced which compensates for the
non-constant coupling efficiencies, caused by local surface
features. In dual-probe operation, only a small share of the
photons emitted by the illumination probe finally reaches
the detection probe. Hence, the different loss mechanisms,
which are accounted for the strong attenuation of the
propagating light, are theoretically investigated by means
of a ray-tracing approach. Ray-tracing allows to examine the
loss mechanisms separately. The simulation reveals, that for
a wavelength of 750nm the intensity decay within the first 5
μm is dominated by the radial distribution of light inside
the layer. At longer distance, absorption is the major
mechanism for a decrease in light intensity. The intensity
decay due to a transmittance at the front interface strongly
attenuates the propagation of light with small angles of
incidence. Although ray-tracing neglects the wave nature of
light, the approach is capable to reproduce the lateral
intensity decay of light propagating in a 1 μm thick
μc-Si:H layer. The ray-tracing approach is supplemented
with finite-difference time-domain (FDTD) simulations which
provide the field distribution on a sub-wavelength scale. By
including the illumination probe to the simulated layer
stack, an improved compliance of simulation and experiment
is achieved. Based on the FDTD simulation, the light
distribution insideand above the layer stack is investigated
and compared to a half-space model which represents a system
without light-trapping properties. It is demonstrated, that
at least for undamaged, perfect probes, a direct light
transfer between illumination and detection probe, bypassing
the absorber layer, is negligible. Furthermore, the FDTD
simulations provide the angular distribution of the light
emitted by a SNOM probe, placed at subwavelength distance
above the surface. Thereby, the simulations complement the
experimentally determined angular resolved far-field
emission characteristic of a probe in air. It is shown that
a large share of $64\%$ of the light intensity emitted by a
SNOM probe, placed at subwavelength distance above a
μc-Si:H absorber layer, is coupled into angles which
exceeds the angle of total reflection. Finally, the
intensity decay of the propagating light, determined by FDTD
simulations, revealed good accordance with the measured
data. A modulation of the intensity decay, which originates
from interference induced by multiple reflections, is
observed in the measurement as well as in FDTD simulations.
The good compliance between simulation and experiment
indicates that macroscopic absorption coefficients are
suitable for the description of light propagation even on
microscopic scales.},
cin = {IEK-5},
cid = {I:(DE-Juel1)IEK-5-20101013},
pnm = {121 - Solar cells of the next generation (POF3-121)},
pid = {G:(DE-HGF)POF3-121},
typ = {PUB:(DE-HGF)11 / PUB:(DE-HGF)3},
url = {https://juser.fz-juelich.de/record/202687},
}