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@ARTICLE{Breunig:202973,
author = {Breunig, Katharina and Spahn, Ingo and Spellerberg, Stefan
and Coenen, Heinrich Hubert},
title = {{P}roduction of no-carrier-added radiobromine: new nickel
selenide target and optimized separation by dry
distillation},
journal = {Radiochimica acta},
volume = {103},
number = {5},
issn = {2193-3405},
address = {Berlin},
publisher = {De @Gruyter},
reportid = {FZJ-2015-05089},
pages = {397-402},
year = {2015},
abstract = {Nickel(II) selenide (NiSe) was investigated as a new
high-current target material for cyclotron production of
radiobromine, as it contains a higher amount of selenium and
has a lower melting point than the widely used Cu2Se. Using
a slanted target system, NiSe was successfully tested up to
beam currents of 16 μA so far. With regard to the
isolation of no-carrier-added (n.c.a.) radiobromide from the
target material, an improved dry distillation device with
high yields of $76\% – 86\%$ was developed. The
implementation of a special custom-made quartz funnel
decreased the dead volume of the apparatus and a quartz
capillary for trapping the radiobromine allowed to
concentrate the radioactivity in a small volume of less than
100 μL of 0.1 M NaOH, ready for immediate subsequent
radiosyntheses. Thus, the new apparatus improves the
handling of the isolation procedure and the radioactive
product. The radiochemical purity of the resulting solution
of n.c.a. [*Br]bromide was verified by radio-IC where no
other species were detected.},
cin = {INM-5},
ddc = {540},
cid = {I:(DE-Juel1)INM-5-20090406},
pnm = {573 - Neuroimaging (POF3-573)},
pid = {G:(DE-HGF)POF3-573},
typ = {PUB:(DE-HGF)16},
UT = {WOS:000353421200008},
doi = {10.1515/ract-2014-2366},
url = {https://juser.fz-juelich.de/record/202973},
}