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@ARTICLE{Yao:203011,
author = {Yao, Jizhong and Kirchartz, Thomas and Vezie, Michelle S.
and Faist, Mark A. and Gong, Wei and He, Zhicai and Wu,
Hongbin and Troughton, Joel and Watson, Trystan and Bryant,
Daniel and Nelson, Jenny},
title = {{Q}uantifying {L}osses in {O}pen-{C}ircuit {V}oltage in
{S}olution-{P}rocessable {S}olar {C}ells},
journal = {Physical review applied},
volume = {4},
number = {1},
issn = {2331-7019},
address = {College Park, Md. [u.a.]},
publisher = {American Physical Society},
reportid = {FZJ-2015-05111},
pages = {014020},
year = {2015},
abstract = {The maximum open-circuit voltage of a solar cell can be
evaluated in terms of its ability to emit light. We herein
verify the reciprocity relation between the
electroluminescence spectrum and subband-gap quantum
efficiency spectrum for several photovoltaic technologies at
different stages of commercial development, including
inorganic, organic, and a type of methyl-ammonium lead-
halide CH3NH3PbI3−xClx perovskite solar cells. Based on
the detailed balance theory and reciprocity relations
between light emission and light absorption, voltage losses
at open circuit are quantified and assigned to specific
mechanisms, namely, absorption edge broadening and
nonradiative recombination. The voltage loss due to
nonradiative recombination is low for inorganic solar cells
(0.04–0.21 V), while for organic solar cell devices it is
larger but surprisingly uniform, with values of 0.34–0.44
V for a range of material combinations. We show that, in
CH3NH3PbI3−xClx perovskite solar cells that exhibit
hysteresis, the loss to nonradiative recombination varies
substantially with voltage scan conditions. We then show
that for different solar cell technologies there is a
roughly linear relation between the power conversion
efficiency and the voltage loss due to nonradiative
recombination.},
cin = {IEK-5},
ddc = {530},
cid = {I:(DE-Juel1)IEK-5-20101013},
pnm = {121 - Solar cells of the next generation (POF3-121)},
pid = {G:(DE-HGF)POF3-121},
typ = {PUB:(DE-HGF)16},
UT = {WOS:000358610300001},
doi = {10.1103/PhysRevApplied.4.014020},
url = {https://juser.fz-juelich.de/record/203011},
}