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@ARTICLE{Menzler:203108,
author = {Menzler, Norbert H. and Sebold, Doris and Fang, Qingping},
title = {{C}hromium-related degradation of thin-film electrolyte
solid oxide fuel cell stacks},
journal = {Journal of the Electrochemical Society},
volume = {162},
number = {12},
issn = {0013-4651},
address = {Pennington, NJ},
publisher = {Electrochemical Soc.},
reportid = {FZJ-2015-05132},
pages = {F1275-F1281},
year = {2015},
abstract = {SOFC short stacks with thin-film electrolyte
anode-supported cells were operated for up to ∼3,000 h and
post-test characterized. The cells consisted of thin
electrolyte films (≤ 3 μm) and LSCF or LSC cathodes.
Typical manganese-oxide chromium evaporation protection
layers and perovskitic cathode contact layers were used.
Operating parameters were: temperatures between 600°C and
750°C, a current density of 500 mA/cm², hydrogen with
$20\%$ water vapor as fuel, and a fuel utilization of
$∼40\%.$ Microstructural characterization revealed that
Cr-containing phases formed at different locations. SEM and
TEM analysis of some cells additionally showed
microstructural changes within the GDC layer. A possible
explanation for the different chromium-containing phase
locations based on theoretical assumptions is given.},
month = {Jul},
date = {2015-07-26},
organization = {Solid Oxide Fuel Cells 14, Glasgow
(United Kingdom), 26 Jul 2015 - 31 Jul
2015},
cin = {IEK-1 / IEK-3},
ddc = {540},
cid = {I:(DE-Juel1)IEK-1-20101013 / I:(DE-Juel1)IEK-3-20101013},
pnm = {135 - Fuel Cells (POF3-135) / SOFC - Solid Oxide Fuel Cell
(SOFC-20140602)},
pid = {G:(DE-HGF)POF3-135 / G:(DE-Juel1)SOFC-20140602},
typ = {PUB:(DE-HGF)16},
UT = {WOS:000363600300053},
doi = {10.1149/2.0101512jes},
url = {https://juser.fz-juelich.de/record/203108},
}