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001     203108
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100 1 _ |0 P:(DE-Juel1)129636
|a Menzler, Norbert H.
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111 2 _ |a Solid Oxide Fuel Cells 14
|c Glasgow
|d 2015-07-26 - 2015-07-31
|g SOFC-XIV
|w United Kingdom
245 _ _ |a Chromium-related degradation of thin-film electrolyte solid oxide fuel cell stacks
260 _ _ |a Pennington, NJ
|b Electrochemical Soc.
|c 2015
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520 _ _ |a SOFC short stacks with thin-film electrolyte anode-supported cells were operated for up to ∼3,000 h and post-test characterized. The cells consisted of thin electrolyte films (≤ 3 μm) and LSCF or LSC cathodes. Typical manganese-oxide chromium evaporation protection layers and perovskitic cathode contact layers were used. Operating parameters were: temperatures between 600°C and 750°C, a current density of 500 mA/cm², hydrogen with 20% water vapor as fuel, and a fuel utilization of ∼40%. Microstructural characterization revealed that Cr-containing phases formed at different locations. SEM and TEM analysis of some cells additionally showed microstructural changes within the GDC layer. A possible explanation for the different chromium-containing phase locations based on theoretical assumptions is given.
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|a Sebold, Doris
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|a Fang, Qingping
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