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@ARTICLE{Andr:203200,
author = {Andrä, Michael and Gunkel, Felix and Bäumer, Christoph
and Xu, Chencheng and Dittmann, Regina and Waser, Rainer},
title = {{T}he influence of the local oxygen vacancy concentration
on the piezoresponse of strontium titanate thin films},
journal = {Nanoscale},
volume = {7},
number = {34},
issn = {2040-3372},
address = {Cambridge},
publisher = {RSC Publ.},
reportid = {FZJ-2015-05198},
pages = {14351-14357},
year = {2015},
abstract = {n this study, the influence of the local oxygen vacancy
concentration on piezoresponse force microscopy (PFM)
measurements was investigated. Ultra-thin single-crystalline
SrTiO3 thin films were deposited on niobium doped SrTiO3
substrates and analyzed using a combined PFM and local
conductive atomic force microscopy (LC-AFM) measurement
setup. After applying different polarization voltages
between ±2 V and ±5 V to the thin films, we simultaneously
observed an anomalous contrast in the piezoresponse
amplitude and phase signal as well as a changed local
conductivity in the exact same region. Since classic
ferroelectricity can be excluded as the reason for the
observed contrast, an influence of the local oxygen vacancy
concentration on the piezoresponse is considered.
Additionally, the surface potential was measured using
Kelvin probe force microscopy (KPFM) revealing a change in
surface potential in the regions of the applied voltage. The
observed relaxation of the surface potential over time was
fitted to a local oxidation reaction of the previously
reduced regions of the ultra-thin SrTiO3 film. We propose a
model that relates the local oxygen vacancy concentration to
the surface potential. The influence of the oxygen vacancy
concentration on the PFM measurements is explained.},
cin = {PGI-7},
ddc = {600},
cid = {I:(DE-Juel1)PGI-7-20110106},
pnm = {524 - Controlling Collective States (POF3-524)},
pid = {G:(DE-HGF)POF3-524},
typ = {PUB:(DE-HGF)16},
UT = {WOS:000360117200020},
doi = {10.1039/C5NR03643G},
url = {https://juser.fz-juelich.de/record/203200},
}