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@ARTICLE{Karl:20324,
      author       = {Karl, M. and Dye, C. and Schmidbauer, N. and Wisthaler, A.
                      and Mikoviny, T. and D'Anna, B. and Müller, M. and Borrás,
                      E. and Clemente, E. and Munoz, A. and Porras, R. and
                      Ródenas, M. and Vázquez, M. and Brauers, T.},
      title        = {{S}tudy of {OH}-initiated degradation of 2-aminoethanol},
      journal      = {Atmospheric chemistry and physics},
      volume       = {12},
      issn         = {1680-7316},
      address      = {Katlenburg-Lindau},
      publisher    = {EGU},
      reportid     = {PreJuSER-20324},
      pages        = {1881 - 1901},
      year         = {2012},
      note         = {The Instituto Universitario CEAM-UMH is partly supported by
                      Generalitat Valenciana, Fundacion Bancaja, and the projects
                      GRACCIE (Consolider-Ingenio 2010) and FEEDBACKS (Prometeo -
                      Generalitat Valenciana). The EUPHORE team is acknowledged
                      for their support in the use of the facilities. Armin
                      Wisthaler and Tomas Mikoviny acknowledge support from A.
                      Hansel and T. D. Mark. Claus Nielsen is thanked for the
                      preparation of the reference salt, ethanolaminium nitrate,
                      for the AMS analysis. Eldbjorg S. Heimstad and Mikael Harju
                      (NILU Tromso) are thanked for determination of rate
                      constants of several products from OH-initiated oxidation of
                      MEA using EPI Suite version 4.0.},
      abstract     = {The degradation of 2-aminoethanol (MEA) by the hydroxyl
                      radical (OH) was studied in the European Photoreactor
                      (EUPHORE), a large outdoor environmental chamber.
                      High-Temperature Proton-Transfer-Reaction Mass Spectrometry
                      (HT-PTR-MS) and Fast Fourier Transform Infrared (FT-IR) were
                      used to follow concentrations of reactants in the gas phase.
                      Aerosol mass concentrations were tracked with Aerosol Mass
                      Spectrometry (AMS). The chamber aerosol model MAFOR was
                      applied to quantify losses of MEA to the particle phase. The
                      rate constant k(OH + MEA) was determined relative to the
                      rate constant of the 1,3,5-trimethylbenzene reaction with OH
                      and was found to be (9.2 +/- 1.1) x 10(-11) cm(3)
                      molecule(-1) s(-1), and thus the reaction between OH
                      radicals and MEA proceeds a factor of 2-3 faster than
                      estimated by structure-activity relationship (SAR) methods.
                      Main uncertainty of the relative rate determination is the
                      unknown temporal behaviour of the loss rate of MEA to
                      chamber wall surfaces during the sunlit experiments.
                      Nucleation and growth of particles observed in the
                      experiments could be reproduced by the chamber model that
                      accounted for condensation of gaseous oxidation products,
                      condensation of ethanolaminium nitrate and nucleation
                      involving MEA and nitric acid.},
      keywords     = {J (WoSType)},
      cin          = {IEK-8},
      ddc          = {550},
      cid          = {I:(DE-Juel1)IEK-8-20101013},
      pnm          = {Atmosphäre und Klima},
      pid          = {G:(DE-Juel1)FUEK491},
      shelfmark    = {Meteorology $\&$ Atmospheric Sciences},
      typ          = {PUB:(DE-HGF)16},
      UT           = {WOS:000300875900014},
      doi          = {10.5194/acp-12-1881-2012},
      url          = {https://juser.fz-juelich.de/record/20324},
}