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@ARTICLE{Zhuang:203324,
author = {Zhuang, Hao and Yang, Nianjun and Fu, Haiyuan and Zhang,
Lei and Wang, Chun and Huang, Nan and Jiang, Xin},
title = {{D}iamond {N}etwork: {T}emplate-{F}ree {F}abrication and
{P}roperties},
journal = {ACS applied materials $\&$ interfaces},
volume = {7},
number = {9},
issn = {1944-8252},
address = {Washington, DC},
publisher = {Soc.},
reportid = {FZJ-2015-05291},
pages = {5384 - 5390},
year = {2015},
abstract = {A porous diamond network with three-dimensionally
interconnected pores is of technical importance but
difficult to be produced. In this contribution, we
demonstrate a simple, controllable, and “template-free”
approach to fabricate diamond networks. It combines the
deposition of diamond/β-SiC nanocomposite film with a
wet-chemical selective etching of the β-SiC phase. The
porosity of these networks was tuned from 15 to $68\%,$
determined by the ratio of the β-SiC phase in the composite
films. The electrochemical working potential and the
reactivity of redox probes on the diamond networks are
similar to those of a flat nanocrystalline diamond film,
while their surface areas are hundreds of times larger than
that of a flat diamond film (e.g., 490-fold enhancement for
a 3 μm thick diamond network). The marriage of the
unprecedented physical/chemical features of diamond with
inherent advantages of the porous structure makes the
diamond network a potential candidate for various
applications such as water treatment, energy conversion
(batteries or fuel cells), and storage (capacitors), as well
as electrochemical and biochemical sensing.},
cin = {PGI-5},
ddc = {540},
cid = {I:(DE-Juel1)PGI-5-20110106},
pnm = {143 - Controlling Configuration-Based Phenomena (POF3-143)},
pid = {G:(DE-HGF)POF3-143},
typ = {PUB:(DE-HGF)16},
UT = {WOS:000350614600043},
doi = {10.1021/am508851r},
url = {https://juser.fz-juelich.de/record/203324},
}