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@ARTICLE{Ma:203325,
author = {Ma, Yao and Sun, Xiao and Yang, Nianjun and Xia, Junhai and
Zhang, Lei and Jiang, Xin},
title = {{S}hape-{C}ontrolled {G}rowth of {C}arbon {N}anostructures:
{Y}ield and {M}echanism},
journal = {Chemistry - a European journal},
volume = {21},
number = {35},
issn = {0947-6539},
address = {Weinheim},
publisher = {Wiley-VCH},
reportid = {FZJ-2015-05292},
pages = {12370 - 12375},
year = {2015},
abstract = {Carbon nanostructures with precisely controlled shapes are
difficult materials to synthesize. A
facet-selective-catalytic process was thus proposed to
synthesize polymer-linked carbon nanostructures with
different shapes, covering straight carbon nanofiber, carbon
nano Y-junction, carbon nano-hexapus, and carbon
nano-octopus. A thermal chemical vapor deposition process
was applied to grow these multi-branched carbon
nanostructures at temperatures lower than 350 °C. Cu
nanoparticles were utilized as the catalyst and acetylene as
the reaction gas. The growth of those multi-branched
nanostructures was realized through the selective growth of
polymer-like sheets on certain indexed facets of Cu
catalyst. The vapor–facet–solid (VFS) mechanism, a new
growth mode, has been proposed to interpret such a growth in
the steps of formation, diffusion, and coupling of
carbon-containing oligomers, as well as their final
precipitation to form nanostructures on the selective Cu
facets.},
cin = {PGI-5},
ddc = {540},
cid = {I:(DE-Juel1)PGI-5-20110106},
pnm = {143 - Controlling Configuration-Based Phenomena (POF3-143)},
pid = {G:(DE-HGF)POF3-143},
typ = {PUB:(DE-HGF)16},
UT = {WOS:000360093700020},
doi = {10.1002/chem.201500440},
url = {https://juser.fz-juelich.de/record/203325},
}