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000020337 084__ $$2WoS$$aMaterials Science, Ceramics
000020337 1001_ $$0P:(DE-Juel1)130810$$aLustfeld, H.$$b0$$uFZJ
000020337 245__ $$aMetallic electrolyte composites in the framework of the brick-layer model
000020337 260__ $$aAmsterdam [u.a.]$$bElsevier Science$$c2012
000020337 300__ $$a859 - 864
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000020337 520__ $$aIt is well known that the already large dielectric constants of some electrolytes like BaTiO3 can be enhanced further by adding metallic (e.g. Ni, Cu or Ag) nanoparticles. The enhancement can be quite large, a factor of more than 1000 is possible. The consequences for the properties will be discussed in the present paper applying a brick-layer model (BLM) for calculating dc-resistivities of thin layers and a modified one (PBLM) that includes percolation for calculating dielectric properties of these materials. The PBLM results in an at least qualitative description and understanding of the physical phenomena: This model gives an explanation for the steep increase of the dielectric constant below the percolation threshold and why this increase is connected to a dramatic decrease of the breakdown voltage as well as the ability of storing electrical energy. We conclude that metallic electrolyte composites like BaTiO3 are not appropriate for energy storage. (C) 2011 Elsevier Ltd. All rights reserved.
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000020337 65320 $$2Author$$aPercolation
000020337 65320 $$2Author$$aComposites
000020337 65320 $$2Author$$aDielectric properties
000020337 65320 $$2Author$$aBaTiO3 and Titanates
000020337 65320 $$2Author$$aCapacitors
000020337 7001_ $$0P:(DE-Juel1)130894$$aPithan, C.$$b1$$uFZJ
000020337 7001_ $$0P:(DE-HGF)0$$aReißel, M.$$b2
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