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@ARTICLE{Gawlitza:203396,
      author       = {Gawlitza, Kornelia and Ivanova, Oxana and Radulescu, Aurel
                      and Holderer, Olaf and von Klitzing, Regine and Wellert,
                      Stefan},
      title        = {{B}ulk {P}hase and {S}urface {D}ynamics of {PEG} {M}icrogel
                      {P}articles},
      journal      = {Macromolecules},
      volume       = {48},
      number       = {16},
      issn         = {1520-5835},
      address      = {Washington, DC},
      publisher    = {Soc.},
      reportid     = {FZJ-2015-05339},
      pages        = {5807 - 5815},
      year         = {2015},
      abstract     = {The adsorption of ethylene glycol (EG) based microgel
                      particles at silicon surfaces was studied. Monodisperse
                      p-MeO2MA-co-OEGMA microgel particles were synthesized by
                      precipitation polymerization. Translational and inner
                      dynamics of p-ME3O5 and p-ME3O26 microgels in bulk were
                      investigated by dynamic light scattering (DLS) and neutron
                      spin echo spectroscopy in transmission geometry (NSE). Here,
                      cooperative diffusion and Zimm type dynamics were observed.
                      The inner dynamics of these microgel particles in adsorbed
                      state was explored by neutron spin echo spectroscopy under
                      grazing incidence (GINSES). The reported GINSES experiments
                      demonstrate the feasibility of these surface sensitive
                      measurements. It indicates a slowing down of the inner
                      dynamics in the vicinity of the substrate. At increasing
                      distance from the substrate, the relaxation is comparable to
                      the bulk.},
      cin          = {JCNS (München) ; Jülich Centre for Neutron Science JCNS
                      (München) ; JCNS-FRM-II / Neutronenstreuung ; JCNS-1},
      ddc          = {540},
      cid          = {I:(DE-Juel1)JCNS-FRM-II-20110218 /
                      I:(DE-Juel1)JCNS-1-20110106},
      pnm          = {6G15 - FRM II / MLZ (POF3-6G15) / 6G4 - Jülich Centre for
                      Neutron Research (JCNS) (POF3-623)},
      pid          = {G:(DE-HGF)POF3-6G15 / G:(DE-HGF)POF3-6G4},
      experiment   = {EXP:(DE-MLZ)KWS2-20140101 / EXP:(DE-MLZ)J-NSE-20140101},
      typ          = {PUB:(DE-HGF)16},
      UT           = {WOS:000360324400043},
      doi          = {10.1021/acs.macromol.5b00788},
      url          = {https://juser.fz-juelich.de/record/203396},
}