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000203398 1001_ $$0P:(DE-Juel1)130679$$aGupta, Sudipta$$b0$$eCorresponding author
000203398 245__ $$aDynamic phase diagram of soft nanocolloids
000203398 260__ $$aCambridge$$bRSC Publ.$$c2015
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000203398 520__ $$aWe present a comprehensive experimental and theoretical study covering micro-, meso- and macroscopic length and time scales, which enables us to establish a generalized view in terms of structure–property relationship and equilibrium dynamics of soft colloids. We introduce a new, tunable block copolymer model system, which allows us to vary the aggregation number, and consequently its softness, by changing the solvophobic-to-solvophilic block ratio (m : n) over two orders of magnitude. Based on a simple and general coarse-grained model of the colloidal interaction potential, we verify the significance of interaction length σint governing both structural and dynamic properties. We put forward a quantitative comparison between theory and experiment without adjustable parameters, covering a broad range of experimental polymer volume fractions (0.001 ≤ ϕ ≤ 0.5) and regimes from ultra-soft star-like to hard sphere-like particles, that finally results in the dynamic phase diagram of soft colloids. In particular, we find throughout the concentration domain a strong correlation between mesoscopic diffusion and macroscopic viscosity, irrespective of softness, manifested in data collapse on master curves using the interaction length σint as the only relevant parameter. A clear reentrance in the glass transition at high aggregation numbers is found, recovering the predicted hard-sphere (HS) value in the hard-sphere like limit. Finally, the excellent agreement between our new experimental systems with different but already established model systems shows the relevance of block copolymer micelles as a versatile realization of soft colloids and the general validity of a coarse-grained approach for the description of the structure and dynamics of soft colloids.
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000203398 7001_ $$0P:(DE-HGF)0$$aCamargo, Manuel$$b1
000203398 7001_ $$0P:(DE-Juel1)130986$$aStellbrink, Jörg$$b2$$ufzj
000203398 7001_ $$0P:(DE-Juel1)130501$$aAllgaier, J.$$b3$$ufzj
000203398 7001_ $$0P:(DE-Juel1)130905$$aRadulescu, Aurel$$b4$$ufzj
000203398 7001_ $$0P:(DE-HGF)0$$aLindner, Peter$$b5
000203398 7001_ $$0P:(DE-HGF)0$$aZaccarelli, Emanuela$$b6
000203398 7001_ $$0P:(DE-HGF)0$$aLikos, Christos N.$$b7
000203398 7001_ $$0P:(DE-Juel1)130917$$aRichter, Dieter$$b8$$ufzj
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