TY  - JOUR
AU  - Drozdov, I. V.
AU  - Kochubey, V.
AU  - Meng, Li
AU  - Mauer, G.
AU  - Vassen, Robert
AU  - Stöver, Detlev
TI  - Modelling and proper evaluation of volumetric kinetics of hydrogen desorption by metal hydrides
JO  - International journal of hydrogen energy
VL  - 40
IS  - 32
SN  - 0360-3199
CY  - New York, NY [u.a.]
PB  - Elsevier
M1  - FZJ-2015-05361
SP  - 10111 - 10122
PY  - 2015
AB  - A simple model of the hydrogen desorption kinetics of metal hydrides is formulated and solved analytically. The particle surface reaction is assumed to be a rate-controlling-step. Then a volumetric measurement of hydrogen desorption process is evaluated on an example of wet ball milled magnesium hydride, and can be applied generally for any metal hydride.The solution reproduces the shape of experimental curves for desorption process. In the case of surface-controlled kinetics, a volumetric measurement requires a special evaluation of results, predicted by the solution of the model. An improved evaluation of the volumetric measurement of hydrogen desorption from magnesium hydride powders using the model has been demonstrated.
LB  - PUB:(DE-HGF)16
UR  - <Go to ISI:>//WOS:000359030100026
DO  - DOI:10.1016/j.ijhydene.2015.05.119
UR  - https://juser.fz-juelich.de/record/203420
ER  -