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@ARTICLE{Schfer:203426,
      author       = {Schäfer, Anna and Rahmanizadeh, K. and Bihlmayer, G. and
                      Luysberg, M. and Wendt, F. and Besmehn, A. and Fox, A. and
                      Schnee, M. and Niu, G. and Schroeder, T. and Mantl, S. and
                      Hardtdegen, H. and Mikulics, M. and Schubert, J.},
      title        = {{P}olymorphous {G}d{S}c{O}$_{3}$ as high permittivity
                      dielectric},
      journal      = {Journal of alloys and compounds},
      volume       = {651},
      issn         = {0925-8388},
      address      = {Lausanne},
      publisher    = {Elsevier},
      reportid     = {FZJ-2015-05367},
      pages        = {514–520},
      year         = {2015},
      abstract     = {Four different polymorphs of GdScO3 are assessed
                      theoretically and experimentally with respectto their
                      suitability as a dielectric. The calculations carried out by
                      density functional theory reveallattice constants, band gaps
                      and the energies of formation of three crystal phases.
                      Experimentallyall three crystal phases and the amorphous
                      phase can be realized as thin films by pulsed
                      laserdeposition using various growth templates. Their
                      respective crystal structures are confirmed byx-ray
                      diffraction and transmission electron microscopy reflecting
                      the calculated lattice constants.X-ray photoelectron
                      spectroscopy unveils the band gaps of the different
                      polymorphs of GdScO3which are above 5 eV for all films
                      demonstrating good insulating properties. From
                      capacitancevoltage measurements, high permittivities of up
                      to 27 for hexagonal GdScO3 are deduced.},
      cin          = {PGI-9 / JARA-FIT / PGI-1 / PGI-5 / PGI-6 / IAS-1 / ZEA-3},
      ddc          = {670},
      cid          = {I:(DE-Juel1)PGI-9-20110106 / $I:(DE-82)080009_20140620$ /
                      I:(DE-Juel1)PGI-1-20110106 / I:(DE-Juel1)PGI-5-20110106 /
                      I:(DE-Juel1)PGI-6-20110106 / I:(DE-Juel1)IAS-1-20090406 /
                      I:(DE-Juel1)ZEA-3-20090406},
      pnm          = {142 - Controlling Spin-Based Phenomena (POF3-142) / 521 -
                      Controlling Electron Charge-Based Phenomena (POF3-521)},
      pid          = {G:(DE-HGF)POF3-142 / G:(DE-HGF)POF3-521},
      typ          = {PUB:(DE-HGF)16},
      UT           = {WOS:000361830700076},
      doi          = {10.1016/j.jallcom.2015.08.135},
      url          = {https://juser.fz-juelich.de/record/203426},
}