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@ARTICLE{Greben:203497,
author = {Greben, Kyrylo and Li, Pinggui and Mayer, Dirk and
Offenhäusser, Andreas and Wördenweber, Roger},
title = {{I}mmobilization and {S}urface {F}unctionalization of
{G}old {N}anoparticles {M}onitored via {S}treaming
{C}urrent/{P}otential {M}easurements},
journal = {The journal of physical chemistry / B},
volume = {119},
number = {19},
issn = {1520-5207},
address = {Washington, DC},
publisher = {Soc.},
reportid = {FZJ-2015-05418},
pages = {5988 - 5994},
year = {2015},
abstract = {A streaming current/potential method is optimized and used
for the analysis of the variation of the surface potential
upon chemical modifications of a complex interface
consisting of different organic molecules and gold
nanoparticles (AuNPs). The surfaces of Si/SiO2 substrates
modified with 3-aminopropyltriethoxysilane (APTES), AuNPs,
and 11-amino-1-undecanethiol (aminothiols) are analyzed via
pH and time dependent zeta potential measurements that
reveal the stability and modification of the surface and
identify crucial parameters for each individual preparation
step. For instance, surface activation and especially
molecular adsorbate layers tend not to be stable in time,
whereas the substrate and the AuNPs provide a stable surface
potential as long as impurities are avoided. It is shown
that the streaming potential/current technique represents an
ideal tool to analyze and monitor the complex surfaces and
their modification.},
cin = {PGI-8 / ICS-8 / JARA-FIT},
ddc = {530},
cid = {I:(DE-Juel1)PGI-8-20110106 / I:(DE-Juel1)ICS-8-20110106 /
$I:(DE-82)080009_20140620$},
pnm = {523 - Controlling Configuration-Based Phenomena (POF3-523)},
pid = {G:(DE-HGF)POF3-523},
typ = {PUB:(DE-HGF)16},
UT = {WOS:000354911300006},
doi = {10.1021/acs.jpcb.5b02615},
url = {https://juser.fz-juelich.de/record/203497},
}