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100 1 _ |0 P:(DE-Juel1)156469
|a Urbain, F.
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245 _ _ |a Solar water splitting with earth-abundant materials using amorphous silicon photocathodes and Al/Ni contacts as hydrogen evolution catalyst
260 _ _ |a Amsterdam [u.a.]
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520 _ _ |a An all earth-abundant and precious metal-free photocathode based on a low-temperature fabricated amorphous silicon tandem junction is demonstrated to be an efficient device for solar water splitting. With a particular designed Al/Ni layer stack as photocathode/electrolyte contact an onset potential for cathodic photocurrent of 1.7 V vs. RHE and a saturation photocurrent density of 7.2 mA/cm2 were achieved. For a high-cost alternative with a Ag/Pt layer stack an even higher photocathode performance is demonstrated. Above all we present an approach for a dedicated photovoltaic and electrochemical development for solar water splitting.
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